376395-16-3Relevant academic research and scientific papers
3,4-Ethylenedioxypyrrole (EDOP) Monomers with Aromatic Substituents for Parahydrophobic Surfaces by Electropolymerization
Mortier, Claudio,Darmanin, Thierry,Guittard, Frdric
, p. 5188 - 5195 (2015)
In nature, superhydrophobic (low adhesion) and parahydrophobic (high adhesion) properties exist in lotus leaves and red roses, for example. The control in the water adhesion is extremely important for applications in water harvesting, for example. Here, w
3,4-Alkylenedioxypyrroles: Functionalized derivatives as monomers for new electron-rich conducting and electroactive polymers
Zong,Reynolds
, p. 6873 - 6882 (2007/10/03)
New functionalized derivatives of 3,4-ethylenedioxypyrrole (EDOP, 5a) and 3,4-(1,3-propylenedioxy) pyrrole (ProDOP, 5b) as especially electron-rich monomers which yield highly electroactive and stable conducting polymers useful for a diverse set of applications have been synthesized. N-Alkylations of ProDOP were carried out to yield a variety of ProDOP derivatives having alkyl, sulfonatoalkoxy, glyme, and glyme alcohol pendant chains. Iodization of EDOP and ProDOP via iodo-decarboxylation afforded iodo-functionalized derivatives useful for subsequent aryl coupling chemistry. N-Protection and formylation of EDOP, followed by Knoevenagel condensation of the resultant 2-formyl-EDOP with aryl acetonitrile derivatives, led to 1-cyano-2-(2-(3,4-ethylenedioxypyrryl))-1-(2-thienyl)vinylene (23) (Th-CNV-EDOP) and 1-cyano-2-(2-(3,4-ethylenedioxypyrryl))-1-(2-(3,4-ethylenedioxythienyl) vinylene (26) (EDOT-CNV-EDOP). A 14-crown-4-ether 34 based dioxypyrrole was synthesized with a cavity potentially useful for lithium ion coordination and sensing in the resultant electroactive polymer. C-Alkylated ProDOPs (43a, 43b, and 43c) containing octyl, ethylhexyl, and dioctyl substituents appended to the central methylene of the propylene bridge, were prepared as monomers for potentially soluble π-conjugated polymers.
