3769-13-9Relevant academic research and scientific papers
Catalyst economy. Part 2: Sequential metathesis - Kharasch sequences using the Grubbs metathesis catalysts
Edlin, Chris D.,Faulkner, James,Quayle, Peter
, p. 1145 - 1151 (2006)
Sequential ring-closing metathesis (RCM)-Kharasch cyclizations are promoted by the Grubbs metathesis catalysts and provide rapid access to bicyclic lactones and lactams.
PHARMACEUTICAL COMPOSITION FOR USE IN THE TREATMENT AND PREVENTION OF ORTHOPOXVIRUS INFECTIONS AND ASSOCIATED DISEASES
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Paragraph 0095; 0096, (2016/08/03)
Pharmaceutical compositions containing di, tri, and tetracyclic acylhydrazide derivatives of the formula below, for use in the treatment or prophylaxis of viral infections and diseases associated therewith, particularly those viral infections and associated diseases caused by the orthopoxvirus.
A Remarkably Efficient Photochemical Methodology for Endo to Exo Isomerization of Diels-Alder Cycloadducts
Pandey, Bipin,Athawale, Asawari A.,Reddy, Ravinder S.,Dalvi, Pramod V.,Kumar, Pradeep
, p. 1173 - 1176 (2007/10/02)
Irradiation of a solution of ethanol containing Diels-Alder cycloadducts and 10-20 percent (by volume) triethylamine at 300 nm furnishes quantitative yield (>90percent) of corresponding exo isomers.A probable mechanism based on photo-induced electron transfer (PET) has been described.
Synthesis of exo-Bicyclooct-5-ene-dicarboxylic Anhydrides by Thermal Isomerization of trans-Diacids
Weisz, Adrian,Mandelbaum, Asher
, p. 5812 - 5815 (2007/10/02)
Bicyclooct-5-ene-trans-1,2-dicarboxylic acid and substituted analogues afford mixtures of the corresponding exo- and endo-anhydrides upon heating at 250-300 deg C.This isomerization provides a practical pathway to substituted and deuterium-labeled exo-anhydrides which are otherwise difficult to obtain.A mechanistic study shows that retro-diene fragmentation is not involved in the isomerization.
