377-54-8Relevant academic research and scientific papers
Electrophilic reactions of fluorocarbons under the action of aluminum chlorofluoride, a potent Lewis acid
Petrov, V. A.,Krespan, C. G.,Smart, B. E.
, p. 138 - 142 (2007/10/03)
A new Lewis acid - aluminum chlorofluoride - was demonstrated to be an effective catalyst for the isomerisation of fluoroolefins, polyfluorinated epoxides and cyclopropanes.At ambient temperature this catalyst converts perfluorobutadiene-1,3 into perfluorobutyne-2 and perfluoro(4-methylpentene-2) into perfluoro(2-methylpentene-2) in nearly quantitative yield.At 100 deg C, aluminum chlorofluoride causes the cleavage of perfluorinated tertiary amines. - Keywords: Electrophilic reactions; Fluorocarbons; Aluminum chlorofluoride; Lewis acid; NMR spectroscopy
ISOMERIC TRANSFORMATIONS OF INTERNAL PERFLUORINATED α-OXIDES
Zapevalov, A.Ya.,Filyakova, T.I.,Kolenko, I.P.,Kodess, M.I.
, p. 80 - 85 (2007/10/02)
The isomeric transformation of the oxides of internal perfluorinated olefins into ketones by the action of alkali-metal fluorides and antimony pentafluoride were studied.The direction of opening of the α-oxide ring in the unsubstituted perfluorinated olefins in the presence of alkali-metal fluorides is determined largely by steric factors.Opening of the epoxide ring by the action of antimony pentafluoride is equally probable in both possible directions.
