71917-15-2Relevant academic research and scientific papers
FLUOROKETONE COMPOUNDS
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Page/Page column 15, (2008/06/13)
The present invention relates to new fluoroketone compounds from the groups monobromoperfluoroketones, monohydromonobromoperfluoroketones, (perfluoroalkoxy)monobromoperfluoroketones, (fluoroalkoxy)monobromoperfluoroketones, and monochloromonobromoperfluoroketones. These fluoroketone compounds have utility in preventing, controlling and extinguishing fire. These fluoroketone compounds have further utility as additives to reduce or eliminate the flammability of normally flammable working fluids such as refrigerants, foam blowing agents, solvents, aerosol propellants, and sterilants.
STEREOCHEMISTRY OF THE EPOXIDATION OF INTERNAL PERFLUOROALKENES WITH SODIUM HYPOCHLORITE
Filyakova, T.I.,Peschanskii, N.V.,Kodess, M.I.,Zapevalov, A.YA.,Kolenko, I.P.
, p. 327 - 332 (2007/10/02)
The epoxidation of the geometric isomers of internal disubstituted perfluoroalkenes by sodium hypochlorite is stereospecific.The 19F NMR spectra of the cis and trans isomers of internal perfluoroolefin oxides were obtained, and the relationships are discussed.
