377726-66-4

Basic information

• Product Name: Benzenecarboximidoyl chloride, 4-methoxy-N-(1-methylethyl)-
• CAS NO: 377726-66-4
• Molecular Formula: C11H14ClNO
• Molecular Weight: 211.691
• Mol File: 377726-66-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenecarboximidoyl chloride, 4-methoxy-N-(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarboximidoyl chloride, 4-methoxy-N-(1-methylethyl)-(377726-66-4)
• EPA Substance Registry System: Benzenecarboximidoyl chloride, 4-methoxy-N-(1-methylethyl)-(377726-66-4)

Safety Data

• Hazardous Substances Data: 377726-66-4(Hazardous Substances Data)

Upstream product

• 100-07-2 4-methoxy-benzoyl chloride 
• 7464-44-0 4-methoxy-N-(1-methylethyl)benzamide 

Downstream Products

• 1252580-91-8 allyl N-isopropyl-4-methoxybenzimidate 
• 70894-74-5 [(4-methoxyphenyl)methyl](propan-2-yl)amine 

Relevant articles and documents

Hydrogenation of Secondary Amides using Phosphane Oxide and Frustrated Lewis Pair Catalysis

The metal-free catalytic hydrogenation of secondary carboxylic acid amides is developed. The reduction is realized by two new catalytic reactions. First, the amide is converted into the imidoyl chloride by triphosgene (CO(OCCl3)2) using novel phosphorus(V) catalysts. Second, the in situ generated imidoyl chlorides are hydrogenated in high yields by an FLP-catalyst. Mechanistic and quantum mechanical calculations support an autoinduced catalytic cycle for the hydrogenation with chloride acting as unusual Lewis base for FLP-mediated H2-activation.