37775-90-9

Basic information

• Product Name: (S)-methylphenyl-o-tolylphosphine oxide
• CAS NO: 37775-90-9
• Molecular Weight: 230.246
• Mol File: 37775-90-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-methylphenyl-o-tolylphosphine oxide(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-methylphenyl-o-tolylphosphine oxide(37775-90-9)
• EPA Substance Registry System: (S)-methylphenyl-o-tolylphosphine oxide(37775-90-9)

Safety Data

• Hazardous Substances Data: 37775-90-9(Hazardous Substances Data)

Upstream product

• 124081-59-0 (R_P)-α-chlorovinylmethylphenylphosphine oxide 
• 16934-93-3 (S_p)-Menthylmethylphenylphosphinate 
• 4294-57-9 para-methylphenylmagnesium bromide 

Downstream Products

• 29415-52-9 Phenyl-p-methylphenylphosphin 
• 181480-96-6 (S)-methylphenyl-o-tolylphosphine borane 

Relevant articles and documents

A Novel Displacement Route to P-Chiral Phosphine Oxides of High Enantiomeric Purity

Reactions of (R)-(1-chlorovinyl)methylphenylphosphine oxide with aryl and alkenyl Grignard reagents result in highly stereoselective displacement of the halovinyl group and afford virtually enantiomerically pure arylmethyl and alkenylmethylphenylphosphine oxides of inverted configuration at phosphorus.