Tetrahedron Letters p. 6343 - 6346 (1994)
Update date:2022-08-05
Topics:
Cardellicchio, Cosimo
Fiandanese, Vito
Naso, Francesco
Pacifico, Saverio
Reactions of (R)-(1-chlorovinyl)methylphenylphosphine oxide with aryl and alkenyl Grignard reagents result in highly stereoselective displacement of the halovinyl group and afford virtually enantiomerically pure arylmethyl and alkenylmethylphenylphosphine oxides of inverted configuration at phosphorus.
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(1972)
