377776-09-5

Basic information

• Product Name: Cyclohexanol, 2-(2-naphthalenyl)-
• CAS NO: 377776-09-5
• Molecular Formula: C16H18O
• Molecular Weight: 226.318
• Mol File: 377776-09-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanol, 2-(2-naphthalenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanol, 2-(2-naphthalenyl)-(377776-09-5)
• EPA Substance Registry System: Cyclohexanol, 2-(2-naphthalenyl)-(377776-09-5)

Safety Data

• Hazardous Substances Data: 377776-09-5(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 580-13-2 2-bromonaphthalene 
• 54607-03-3 2-(cyclohex-1-en-1-yl)naphthalene 
• 286-20-4 cyclohexane-1,2-epoxide 

Downstream Products

• 167476-37-1 2-naphthyl-1-(tert-butyldimethylsilyloxy)cyclohex-1-ene 
• 167476-36-0 2-naphthyl-1-(trimethylsilyloxy)cyclohex-1-ene 
• 54367-97-4 2-(naphthalen-2-yl)cyclohexan-1-one 

Relevant articles and documents

Method for preparing alcohol through reaction of Suzuki no exogenous alkali (by machine translation)

The method for synthesizing the alcohol compound by. using the method disclosed by the invention for preparing .the alcohol compound by adopting the method Suzuki disclosed by the invention has the advantages that the reaction system, is convenient and convenient, to prepare, and the reaction system is convenient to prepare . Suzuki. (by machine translation)

Enantioselective protonation of silyl enol ethers and ketene disilyl acetals with Lewis acid-assisted chiral Bronsted acids: Reaction scope and mechanistic insights

Enantioselective protonation is a potent and efficient way to construct chiral carbons. Here we report details of the reaction using Lewis acid-assisted chiral Bronsted acids (chiral LBAs). The 1:1 coordinate complex of tin tetrachloride and optically active binaphthol ((R)- or (S)-BINOL) can directly protonate various silyl enol ethers and ketene disilyl acetals to give the corresponding α-aryl ketones and α-arylcarboxylic acids, respectively, with high enantiomeric excesses (up to 98% ee). A catalytic version of enantioselective protonation has also been achieved using stoichiometric amounts of 2,6-dimethylphenol and catalytic amounts of monomethyl ether of optically active BINOL in the presence of tin tetrachloride. This protonation is also effective for producing α-halocarbonyl compounds (up to 91% ee). DFT calculations on the B3LYP/LANL2DZ level show that the conformational structure of the chiral LBA and the orientation of activated proton on (R)-BINOLs are important for understanding the absolute stereochemistry of the products.