37784-33-1Relevant academic research and scientific papers
Cp?Co(III)/MPAA-Catalyzed Enantioselective Amidation of Ferrocenes Directed by Thioamides under Mild Conditions
Liu, Yan-Hua,Li, Peng-Xiang,Yao, Qi-Jun,Zhang, Zhuo-Zhuo,Huang, Dan-Ying,Le, Minh Dong,Song, Hong,Liu, Lei,Shi, Bing-Feng
supporting information, (2019/03/19)
Cp?Cobalt(III)-catalyzed enantioselective C-H amidation of ferrocenes using monoprotected amino acids (MPAAs) as chiral ligands was developed. The reaction was performed under mild conditions in high yields (up to 97%) with moderate enantioselectivity (up to 77.5:22.5 er), providing a promising strategy to create planar chirality via base-metal-catalyzed enantioselective C-H activation.
Genotoxic activity of halogenated phenylglycine derivatives
Boto, Alicia,Gallardo, Juan A.,Hernandez, Rosendo,Ledo, Francisco,Munoz, Ana,Murguia, Jose R.,Menacho-Marquez, Mauricio,Orjales, Aurelio,Saavedra, Carlos J.
, p. 6073 - 6077 (2008/12/22)
The discovery of genotoxic amino acids derived from phenylglycine, and posessing halogen substituents, is described. The utility of hypervalent iodine reagents in the synthesis of this class of compounds is highlighted. The mechanism of action of the (hal
Synthesis of (-)-cytoxazone and (+)-epi-cytoxazone: The chiral pool approach
Tokic-Vujosevic, Zorana,Petrovic, Goran,Rakic, Bojana,Matovic, Radomir,Saicic, Radomir N.
, p. 435 - 447 (2007/10/03)
Immunomodulator (-)-cytoxazone and its epimer (+)-epi-cytoxazone were synthesized starting from (D)-(-)-4-hydroxyphenylglycine. Homologation of the amino acid was achieved via the corresponding aldehyde, by a cyanohydrin reaction. The racemization of high
CHEMO-ENZYMATIC ASYMMETRIC SYNTHESIS OF AMINO ACIDS. ENANTIOSELECTIVE HYDROLYSES OF 2-PHENYL-OXAZOLIN-5-ONES.
Gu, Rui-Lin,Lee, Ik-Soo,Sih, Charles J.
, p. 1953 - 1956 (2007/10/02)
Porcine pancreatic lipase and the lipase of Aspergillus niger catalyze the enantioselective hydrolysis of a series of 4-substituted-2-phenyl-oxazolin-5-ones to yield optically active (S)- and (R)-N-benzoyl amino acids respectively.
