378238-86-9

Upstream product

• 4005-49-6 N-benzoyladenine 
• 378238-84-7 (2S,3S,3aR,5R,6R,6aS)-6-Acetoxy-5-(6-benzoylamino-purin-9-yl)-2-ethoxycarbonylmethyl-3-phenylsulfanyl-hexahydro-furo[3,2-b]furan-2-carboxylic acid ethyl ester 
• 378238-83-6 (2S,3S,3aR,6R,6aS)-5,6-Diacetoxy-2-ethoxycarbonylmethyl-3-phenylsulfanyl-hexahydro-furo[3,2-b]furan-2-carboxylic acid ethyl ester 
• 378238-82-5 (3aR,3bS,5S,6S,6aR,7aR)-5-Ethoxycarbonylmethyl-2,2-dimethyl-6-phenylsulfanyl-hexahydro-furo[2',3':4,5]furo[2,3-d][1,3]dioxole-5-carboxylic acid ethyl ester 
• 378238-89-2 tert-Butyl-[(3aR,5R,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yloxy]-diphenyl-silane 
• 378238-90-5 [1-[(3aR,5R,6R,6aR)-6-(tert-Butyl-diphenyl-silanyloxy)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl]-meth-(E)-ylidene]-hydrazine 
• 378238-77-8 tert-Butyl-{(3aR,6S,6aR)-5-[1-iodo-meth-(E)-ylidene]-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yloxy}-diphenyl-silane 
• 378238-76-7 3-O-(tert-butyldiphenylsilyl)-1,2-O-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose 
• 378238-79-0 (E)-2-{(3aR,6S,6aR)-5-[1-Iodo-meth-(E)-ylidene]-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yloxy}-but-2-enedioic acid diethyl ester 
• 378238-81-4 (3aR,3bS,5R,7aR)-5-Ethoxycarbonylmethyl-2,2-dimethyl-3a,3b,5,7a-tetrahydro-furo[2',3':4,5]furo[2,3-d][1,3]dioxole-5-carboxylic acid ethyl ester 
• 378238-91-6 (3aR,6S,6aR)-5-[1-Iodo-meth-(E)-ylidene]-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol 
• 762-21-0 acetylenedicarboxylic acid diethyl ester 
• 378238-85-8 (2S,3S,3aR,5R,6R,6aS)-6-Acetoxy-3-benzenesulfinyl-5-(6-benzoylamino-purin-9-yl)-2-ethoxycarbonylmethyl-hexahydro-furo[3,2-b]furan-2-carboxylic acid ethyl ester 

Downstream Products

• 378238-87-0 (2R,5R,6R,6aS)-5-(6-Benzoylamino-purin-9-yl)-2-carboxymethyl-6-hydroxy-2,5,6,6a-tetrahydro-furo[3,2-b]furan-2-carboxylic acid 

Relevant academic research and scientific papers

Synthesis of griseolic acid B by pi-face-dependent radical cyclization.

[reaction: see text]. Radical cyclization of 6 affords the bicyclic vinyl ether 9 with the appropriate stereochemistry for elaboration (seven steps) to griseolic acid B (1).