378251-01-5Relevant academic research and scientific papers
Highly stereoselective asymmetric construction of an acyclic carbon skeleton having two adjacent alkyl substituents by Michael addition of optically active allenyltitaniums to alkylidenemalonates
Song, Yongcheng,Okamoto, Sentaro,Sato, Fumie
, p. 3543 - 3545 (2001)
(matrix presented) Enantio-enriched allenyltitaniums prepared in situ by the reaction of optically active secondary propargyl phosphates with a divalent titanium reagent Ti(O-i-Pr)4/2i-PrMgCl react readily with alkylidenemalonates with excellen
