37844-24-9

Usage

InChI:InChI=1/C9H9N3OS2/c1-13-7-4-2-6(3-5-7)10-8-11-12-9(14)15-8/h2-5H,1H3,(H,10,11)(H,12,14)

Upstream product

• 75-15-0 carbon disulfide 
• 40207-03-2 p-Anisidinothioformyl-hydrazin 
• 125908-33-0 1-ethyl-6-(4'-methoxyphenyl)-2,5-dithiobiurea 
• 125908-40-9 1-propyl-6-(4'-methoxyphenyl)-2,5-dithiobiurea 
• 125908-41-0 1-butyl-6-(4'-methoxyphenyl)-2,5-dithiobiurea 
• 125908-29-4 1-methyl-6-(4'-methoxyphenyl)-2,5-dithiobiurea 

Downstream Products

• 73311-04-3 (5-ethylsulfanyl-[1,3,4]thiadiazol-2-yl)-(4-methoxy-phenyl)-amine 
• 52494-19-6 [5-(4-methoxy-anilino)-[1,3,4]thiadiazol-2-ylsulfanyl]-acetic acid ethyl ester 
• 68161-41-1 [5-(4-methoxy-anilino)-[1,3,4]thiadiazol-2-ylsulfanyl]-acetic acid 
• 52494-26-5 [5-(4-methoxy-anilino)-[1,3,4]thiadiazol-2-ylsulfanyl]-acetic acid hydrazide 
• 21123-81-9 5-(4-methoxy-anilino)-4-p-tolyl-2,4-dihydro-[1,2,4]triazole-3-thione 
• 21123-57-9 N-(4-methoxy-phenyl)-N'-p-tolyl-[1,3,4]thiadiazole-2,5-diamine 
• 21123-67-1 5-(4-methoxy-anilino)-4-(4-methoxy-phenyl)-2,4-dihydro-[1,2,4]triazole-3-thione 
• 21123-53-5 N,N'-bis-(4-methoxy-phenyl)-[1,3,4]thiadiazole-2,5-diamine 
• 21123-79-5 5-(4-methoxy-anilino)-4-phenyl-2,4-dihydro-[1,2,4]triazole-3-thione 
• 21123-55-7 N-(4-methoxy-phenyl)-N'-phenyl-[1,3,4]thiadiazole-2,5-diamine 

Relevant academic research and scientific papers

an interesting isomerization: synthesis of mesoionic 5-arylamino-1,3,4-thiadiazolium-2-thiolates by using ω-bromo-ω-(1H-1,2,4-triazol-1-yl)acetophenone as catalyst

Mesoionic 5-arylamino-1,3,4-thiadiazolium-2-thiolates 7a-f were prepared by the isomerization of 5-arylamino-1,3,4-thiadiazol-2-thiones 5a-f by using ω-bromo-ω-(1H-1,2,4-triazol-1-yl)acetophenone 6 as catalyst. All the structures of mesoionic synthesized were confirmed by elemental analyses, 1H NMR, IR and MS spectral data. We have also determined the x-ray photoelectron spectroscopy (XPS) of the mesoionic and their precursors. A comparison of XPS spectra between the mesoionic and their precursors showed that the charge separation in mesoionic is distinctly larger than in their precursors.

Alkali catalyzed thermal cyclization of 1-substituted and 1,6-disubstituted 2,5-dithiobiureas: Formation of 1,2,4-triazolidine-3,5-dithiones and/or 1,3,4-thiadiazoline-5-thiones

Alkali catalyzed thermal cyclization of 1-alkyl and 1,6-dialkyl-2,5-dithiobiureas (I, R=alkyl, R'=H and R=R'=alkyl) results in the formation of 4-alkyl-1,2,4-triazolidine-3,5-dithiones (V) (alkyl=Me or Et) and 2-alkylamino-Δ2-1,3,4-thiadiazoline-5-thiones (VI) (alkyl=n-Pr or n-Bu).Under the same conditions, 1-alkyl-6-aryl-2,5-dithiobiureas (I, R=alkyl, R'=aryl) give 2-arylamino-Δ2-1,3,4-thiadiazoline-5-thiones (IX) (alkyl=Me, Et, n-Pr or n-Bu) and 4-alkyl-1,2,4-triazolidine-3,5-dithiones (V) also when the alkyl groups are Me or Et.