379-47-5

Basic information

• Product Name: triphenylgermanium fluoride
• Synonyms: triphenylgermanium fluoride
• CAS NO: 379-47-5
• Molecular Weight: 322.906
• Mol File: 379-47-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: triphenylgermanium fluoride(CAS DataBase Reference)
• NIST Chemistry Reference: triphenylgermanium fluoride(379-47-5)
• EPA Substance Registry System: triphenylgermanium fluoride(379-47-5)

Safety Data

• Hazardous Substances Data: 379-47-5(Hazardous Substances Data)

Upstream product

• 2816-43-5 triphenylgermane 
• 429-42-5 tetrabutylammonium tetrafluoroborate 
• 7664-39-3 hydrogen fluoride 
• 2181-40-0 bis(triphenylgermyl)oxide 
• 67969-82-8 tetrafluoroboric acid diethyl ether 
• 1626-24-0 chlorotriphenylgermane 
• 420-60-0 trimethyltin fluoride 
• 150746-76-2 tris(dimethylamino)sulfonium trimethylsilyldifluoride 
• 1048-05-1 tetraphenylgermane 
• 126298-04-2 Ge(C₆H₅)3NH₂ 
• 53445-89-9 triphenylmethoxygermane 
• 23082-96-4 bis(triphenylgermyl)mercury 
• 12332-08-0 difluorogermylene 

Downstream Products

• 2816-43-5 triphenylgermane 
• 2816-39-9 hexaphenyldigermane 
• 1529-27-7 Triphenylgermanol 
• 2181-40-0 bis(triphenylgermyl)oxide 
• 1048-05-1 tetraphenylgermane 
• 149165-59-3 ((C₆H₅)3Ge)3N 
• 22052-37-5 Bis-(triphenylgermyl)-amin 
• 1626-24-0 chlorotriphenylgermane 
• 3005-32-1 triphenylgermanium bromide 

Relevant articles and documents

Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge-F bond activation

Pd/Ni → Ge-F interactions supported by phosphine-chelation were found to trigger dual activation of Ge-F bonds under mild conditions. This makes fluoro germanes suitable partners for catalytic Ge-C cross-coupling and enables Germa-Suzuki reactions to be a

Hydride-carbyne to carbene transformation in a cyclopentadienyl-osmium complex: An alternative to the single hydride-Cα migration

Complexes OsH(η5-C5H5)(C≡CPh)(EPh3)( PiPr3) [E = Si (1), Ge (2)] react with 2.0 equiv of HBF4·OEt2 to give [OsH(η5-C5H5)(≡C-CH2Ph)(P iPr3)]BF4 (3). Treatment of 3 with KOH affords OsH(η5-C5H5)(=C=CHPh)(PiPr3 ) (5) in equilibrium with the metalated species OsH(η5-C5H5)(o-C6H4CH =CH)(PiPr3) (7) ΔH° = -3.6 ± 0.2 kcal mol-1 and ΔS° = -10.8 ± 1.9 cal K-1 mol -1 for the formation of 7). The addition of P(OMe)3 to the solution of the isomeric mixture leads to Os(η5-C5H5){(E)-CH=CHPh}{P(OMe)3 }(PiPr3) (8), which reacts with HBF4·OEt2 to give [Os(η5-C5H5)(=CHCH2Ph){P(OMe) 3}(PiPr3)]BF4 (4).