37913-72-7

Upstream product

• 98-03-3 thiophene-2-carbaldehyde 
• 2243-53-0 styrylacetic acid 
• 14756-03-7 3-(2-thienyl)acrolein 
• 103-82-2 phenylacetic acid 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 39511-11-0 (E)-1-phenyl-3-(thiophen-2-yl)-2-propen-1-one 

Downstream Products

• 103348-56-7 2-(1,6,7,7-Tetrachloro-5-phenyl-bicyclo[4.1.0]hept-3-en-2-yl)-thiophene 
• 103437-34-9 C₃₄H₂₀S₂ 
• 103348-58-9 C₃₄H₂₀S₂ 
• 103348-57-8 Dichlor-2-phenyl-5(2-thienyl)-bicyclo<4.1.0>hepta-1,3,5-trien 

Relevant academic research and scientific papers

Indium triflate catalyzed rearrangement of aryl-substituted cyclopropyl carbinols to 1,4-disubstituted 1,3-butadienes

Aryl-substituted cyclopropyl carbinol derivatives undergo a facile stereoselective rearrangement catalyzed by In(OTf)3 in dichloromethane under sonication to produce the substituted conjugated all-trans-butadienes. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.

Catalysis by ionic liquids: Cyclopropyl carbinyl rearrangements catalyzed by [pmim]Br under organic solvent free conditions

Aryl substituted cyclopropyl carbinol derivatives undergo stereoselective rearrangements catalyzed by the ionic liquid, 1-methyl-3-pentylimidazolium bromide, under sonication, without any organic solvent, to produce the substituted conjugated all-trans-butadienes.

THE ONE-POT PALLADIUM CATALYZED WITTIG REACTION WITH ALLYLIC ALCOHOLS. SCOPE AND LIMITATIONS

Some allylic alcohols react with aldehydes and triphenylphosphine in a one-pot formal Wittig reaction under Pd0 catalysis.The method has been extended to cinnamyl alcohol, 1, 2-methyl-2-propen-1-ol, 7, and 3-buten-2-ol, 11, and to heterocyclic aldehydes.