3796-62-1

Basic information

• Product Name: 1,3-Dioxolane, 2-(4,8-dimethyl-3,7-nonadienyl)-2-methyl-, (E)-
• CAS NO: 3796-62-1
• Molecular Formula: C15H26O2
• Molecular Weight: 238.37
• Mol File: 3796-62-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,3-Dioxolane, 2-(4,8-dimethyl-3,7-nonadienyl)-2-methyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dioxolane, 2-(4,8-dimethyl-3,7-nonadienyl)-2-methyl-, (E)-(3796-62-1)
• EPA Substance Registry System: 1,3-Dioxolane, 2-(4,8-dimethyl-3,7-nonadienyl)-2-methyl-, (E)-(3796-62-1)

Safety Data

• Hazardous Substances Data: 3796-62-1(Hazardous Substances Data)

Upstream product

• 3796-70-1 trans geranyl acetone 
• 107-21-1 ethylene glycol 
• 7733-91-7 (E)-6,10-dimethyl-5,9-undecadien-2-ol 

Downstream Products

• 1123890-01-6 C₁₇H₂₈O₄ 
• 38748-84-4 (–)-(R)-cembrene A 

Relevant articles and documents

Stereoselective Directed Cationic Cascades Enabled by Molecular Anchoring in Terpene Cyclases

Cascade reactions appeared as a cutting-edge strategy to streamline the assembly of complex structural scaffolds from naturally available precursors in an atom-, as well as time, labor- and cost-efficient way. We herein report a strategy to control cation

Selective rhenium-catalyzed oxidation of secondary alcohols with methyl sulfoxide in the presence of ethylene glycol, a convenient one-pot synthesis of ketals

Formula presented Secondary alcohols are oxidized preferentially by DMSO and the catalyst ReOCl3(PPh3)2 in the presence of ethylene glycol and refluxing toluene, producing the corresponding ketals. The reactions are rapid, and proceed in very good to excellent yields. The byproducts of the reaction, methyl sulfide and water, are easily removed. No epoxidation or other common side reactions were observed. This direct oxidative transformation of alcohols to the protected ketal derivatives should have broad synthetic applicability.