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38748-84-4

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38748-84-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 38748-84-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,8,7,4 and 8 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 38748-84:
(7*3)+(6*8)+(5*7)+(4*4)+(3*8)+(2*8)+(1*4)=164
164 % 10 = 4
So 38748-84-4 is a valid CAS Registry Number.

38748-84-4Downstream Products

38748-84-4Relevant articles and documents

Mechanistic investigations on multiproduct β-himachalene synthase from Cryptosporangium arvum

Rinkel, Jan,Dickschat, Jeroen S.

supporting information, p. 1008 - 1019 (2019/06/08)

A bacterial terpene synthase from Cryptosporangium arvum was characterised as a multiproduct β-himachalene synthase. In vitro studies showed not only a high promiscuity with respect to its numerous sesquiterpene products, including the structurally demanding terpenes longicyclene, longifolene and α-longipinene, but also to its substrates, as additional activity was observed with geranyl- and geranylgeranyl diphosphate. In-depth mechanistic investigations using isotopically labelled precursors regarding the stereochemical course of both 1,11-cyclisation and 1,3-hydride shift furnished a detailed catalytic model suggesting the molecular basis of the observed low product selectivity. The enzyme's synthetic potential was also exploited in the preparation of sesquiterpene isotopomers, which provided insights into their EIMS fragmentation mechanisms.

Novel Synthesis of (-)-(R)-Cembrene A, Synthesis of (+)-(R)-Cembrenene and (+)-(S)-Cembrene

Farkas, Imre,Pfander, Hanspeter

, p. 1980 - 1985 (2007/10/02)

A novel synthesis of (-)-(R)-cembrene A ((-)-3) was developed using the Sharpless epoxidation for the introduction of the chiral center.Furthermore, the synthesis of (+)-(R)-cembrenene ((+)-4) showed that this cembranoid must have the (R)-configuration and not, as previously reported, the (S)-confguration.Selective hydrogebation of (+)-4 afforded (+)-(S)-cembrene ((+)-5).

PREPARATION OF ENANTIOMERICALLY PURE 1-HYDROXY-NEOCEMBRENES TO DETERMINE THE UNSOLVED ABSOLUTE CONFIGURATION OF CEMBRENOIDS

Aoki, Mario,Uyehara, Tadao,Kato, Tadahiro,Kabuto, Kuninobu,Yamaguchi, Shozo

, p. 1121 - 1124 (2007/10/02)

Cis and trans 1-hydroxy-neocembrenes were prepared in an enantiomerically pure form by reduction of dl-ketone with respective (+)- and (-)-Darvon-LiAlH4 complex followed by purification with the aids of esterification with d- and l-menthoxyacetyl chlorides and (-)-camphanic acid chloride, respectively.Absolute configuration of naturally occurring (+)-mayol and (+)-cembrenene was determined by correlation with enantiomerically pure compounds.

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