380456-92-8

Basic information

• Product Name: ((CH₃)3CCH₂)3In*P(H)(CH(CH₃)2)2
• Synonyms: ((CH₃)3CCH₂)3In*P(H)(CH(CH₃)2)2
• CAS NO: 380456-92-8
• Molecular Weight: 446.406
• Mol File: 380456-92-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((CH₃)3CCH₂)3In*P(H)(CH(CH₃)2)2(CAS DataBase Reference)
• NIST Chemistry Reference: ((CH₃)3CCH₂)3In*P(H)(CH(CH₃)2)2(380456-92-8)
• EPA Substance Registry System: ((CH₃)3CCH₂)3In*P(H)(CH(CH₃)2)2(380456-92-8)

Safety Data

• Hazardous Substances Data: 380456-92-8(Hazardous Substances Data)

Upstream product

• 139408-74-5 K⁽¹⁺⁾*{HIn(CH₂C(CH₃)3)3}^(1-)=K{HIn(CH₂C(CH₃)3)3} 
• 40244-90-4 Chlorodiisopropylphosphane 

Relevant articles and documents

Reactions of neopentylindium(III) derivatives with isopropylphosphorus compounds

A 1:1 mixture of In(CH2CMe3)3 and HP(i-Pr)2 at room temperature undergoes a very slow hydrocarbon elimination reaction to form [(Me3CCH2)2InP(i-Pr)2]2 and neopentane. The indium phosphide [(Me3CCH2)2InP(i-Pr)2]2 has also been prepared by reacting KIn(CH2- CMe3)3H with ClP(i-Pr)2 in pentane. When pentane solutions of these reagents were combined at -78°C and then maintained at ～20°C for 2 days, [(Me3CCH2)2InP(i-Pr)2]2, (Me3CCH2)3In·P(H)(i-Pr)2, (Me3CCH2)3In·P2 (i-Pr)4, (Me3CCH2)3In·P (CH2CMe3)(i-Pr)2, H2, indium metal, and KCl were observed. The formation of all products is explained by a set of experimentally verified reactions. An X-ray structural study of [(Me3CCH2)2InP(i-Pr)2]2 shows each molecule to have an unusual puckered four-membered In2P2 core.