38131-82-7Relevant academic research and scientific papers
Transition-Metal-Free Dehydrogenative N–N Coupling of Secondary Amines with KI/KIO4
Yin, Dehang,Jin, Jian
supporting information, p. 5646 - 5649 (2019/08/21)
A transition-metal-free method for the dehydrogenative N–N coupling of secondary amines has been accomplished. This oxidative KI/KIO4 protocol is mild and operationally simple. A diverse range of diphenylamines, carbazoles, and N-alkylanilines readily undergo N–N homo-coupling effectively. Notably, the N–N cross-coupling of two different arylamines is also demonstrated, which provides a straightforward approach to the complex N–N structures.
