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3818-32-4

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3818-32-4 Usage

General Description

3-hydroxy-2,2-bis(hydroxymethyl)propionaldehyde, also known as DHA (Dihydroxyacetone), is a simple carbohydrate that is primarily used as an ingredient in sunless tanning products. It is colorless, and it interacts with the amino acids in dead skin cells to produce a brown color change. This chemical is safe for external use and has been approved by the Food and Drug Administration (FDA) for use in cosmetics, including sunless tanning products. However, it could cause certain side effects like skin irritation when applied excessively or if exposed to sensitive areas like the eyes or the mouth.

Check Digit Verification of cas no

The CAS Registry Mumber 3818-32-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,8,1 and 8 respectively; the second part has 2 digits, 3 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 3818-32:
(6*3)+(5*8)+(4*1)+(3*8)+(2*3)+(1*2)=94
94 % 10 = 4
So 3818-32-4 is a valid CAS Registry Number.
InChI:InChI=1/C5H10O4/c6-1-5(2-7,3-8)4-9/h1,7-9H,2-4H2

3818-32-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-Hydroxy-2,2-bis(hydroxymethyl)propanal

1.2 Other means of identification

Product number -
Other names 3-hydroxy-2,2-bis-hydroxymethyl-propionaldehyde

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3818-32-4 SDS

3818-32-4Synthetic route

formaldehyd
50-00-0

formaldehyd

acetaldehyde
75-07-0

acetaldehyde

tri(hydroxymethyl)acetaldehyde
3818-32-4

tri(hydroxymethyl)acetaldehyde

Conditions
ConditionsYield
With sodium hydroxide; water
With sodium carbonate at 40 - 50℃;
With sodium carbonate at 40 - 50℃;
2-dimethoxymethyl-2-hydroxymethyl-propane-1,3-diol
40364-88-3

2-dimethoxymethyl-2-hydroxymethyl-propane-1,3-diol

tri(hydroxymethyl)acetaldehyde
3818-32-4

tri(hydroxymethyl)acetaldehyde

Conditions
ConditionsYield
With sulfuric acid
formaldehyd
50-00-0

formaldehyd

acetaldehyde
75-07-0

acetaldehyde

A

Pentaerythritol
115-77-5

Pentaerythritol

B

tri(hydroxymethyl)acetaldehyde
3818-32-4

tri(hydroxymethyl)acetaldehyde

C

Dipentaerythritol
126-58-9

Dipentaerythritol

D

tripentaerythritol
78-24-0

tripentaerythritol

E

3-(3-Hydroxy-2,2-bis-hydroxymethyl-propoxy)-2,2-bis-hydroxymethyl-propionaldehyde

3-(3-Hydroxy-2,2-bis-hydroxymethyl-propoxy)-2,2-bis-hydroxymethyl-propionaldehyde

F

3-[3-(3-Hydroxy-2,2-bis-hydroxymethyl-propoxy)-2,2-bis-hydroxymethyl-propoxy]-2,2-bis-hydroxymethyl-propionaldehyde

3-[3-(3-Hydroxy-2,2-bis-hydroxymethyl-propoxy)-2,2-bis-hydroxymethyl-propoxy]-2,2-bis-hydroxymethyl-propionaldehyde

Conditions
ConditionsYield
With sodium hydroxide at 30℃; Product distribution; Mechanism; pH=12.5; different initial acetaldehyde concentrations;
dimethoxymethyl-hydroxymethyl-malonic acid dimethyl ester
40364-87-2

dimethoxymethyl-hydroxymethyl-malonic acid dimethyl ester

tri(hydroxymethyl)acetaldehyde
3818-32-4

tri(hydroxymethyl)acetaldehyde

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: LiAlH4 / diethyl ether
2: aq. H2SO4
View Scheme
Pentaerythritol
115-77-5

Pentaerythritol

tri(hydroxymethyl)acetaldehyde
3818-32-4

tri(hydroxymethyl)acetaldehyde

Conditions
ConditionsYield
With potassium nitrate at 298.2℃; Kinetics; Catalytic behavior; Mechanism; Temperature; Alkaline conditions;
formaldehyd
50-00-0

formaldehyd

tri(hydroxymethyl)acetaldehyde
3818-32-4

tri(hydroxymethyl)acetaldehyde

aqueous NaOH-solution

aqueous NaOH-solution

Pentaerythritol
115-77-5

Pentaerythritol

Conditions
ConditionsYield
at 0 - 41℃; Rate constant;
tri(hydroxymethyl)acetaldehyde
3818-32-4

tri(hydroxymethyl)acetaldehyde

water
7732-18-5

water

triacetate of tris-hydroxymethyl-acetaldehyde

triacetate of tris-hydroxymethyl-acetaldehyde

3818-32-4Downstream Products

3818-32-4Relevant articles and documents

-

Peters,Cupit

, p. 57 (1959)

-

ANALYSIS OF THE STRUCTURE OF THE REACTION SYSTEM OF A PROCESS ON THE BASIS OF INTEGRAL CHARACTERISTICS.

Belkin

, p. 341 - 345 (2007/10/02)

In this work the structure of the reactions of the acetaldehyde-formaldehyde condensation process is subjected to systems analysis, based on the dependence of its integral characteristics on the general conditions, and the main routes of detailed experimental verification of the proposed mechanism are suggested.

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