38246-62-7Relevant academic research and scientific papers
Photochemical Generation of μ-Amido-μ-peroxo-bis Complex from the Corresponding μ-Hyperoxo Complex in Neutral Aqueous Solution
Shinohara, Nobuyoshi,Kose, Emiko,Ohkubo, Wataru
, p. 3338 - 3340 (1988)
A μ-amido-μ-hyperoxo complex, -)Co(en)2>4+, was found to generate the corresponding μ-peroxo complex, together with mononuclear cobalt(III) complexes upon irradiation with near-ultraviolet light in a neutral aqueous solution.The result is different from that obtained in an acidic aqoueous solution, in which the products are 3+ and Coaq2+.The photochemical reaction mechanisms are discussed.
