
Bulletin of the Chemical Society of Japan p. 3338 - 3340 (1988)
Update date:2022-08-03
Topics: Photochemical Generation
Shinohara, Nobuyoshi
Kose, Emiko
Ohkubo, Wataru
A μ-amido-μ-hyperoxo complex, <(en)2Co(NH2,O2-)Co(en)2>4+, was found to generate the corresponding μ-peroxo complex, together with mononuclear cobalt(III) complexes upon irradiation with near-ultraviolet light in a neutral aqueous solution.The result is different from that obtained in an acidic aqoueous solution, in which the products are
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