38253-64-4

Basic information

• Product Name: (1R,3S,4R)-3-benzyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
• Synonyms: (1R,3S,4R)-3-benzyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
• CAS NO: 38253-64-4
• Molecular Weight: 242.361
• Mol File: 38253-64-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1R,3S,4R)-3-benzyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,3S,4R)-3-benzyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one(38253-64-4)
• EPA Substance Registry System: (1R,3S,4R)-3-benzyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one(38253-64-4)

Safety Data

• Hazardous Substances Data: 38253-64-4(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 473929-46-3 (1R,4R)-3-[(E)-(dimethylamino)methylidene]-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 
• 15087-24-8 (1R,4S,3E)-3-benzylidene-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 
• 464-49-3 (1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 
• 36065-09-5 1,7,7-trimethyl-3-(1-phenylmethylidene)bicyclo[2.2.1]heptan-2-one 
• 28070-24-8 (1R,4S)-anti-3-benzylidene-exo-1,7,7-trimethyl-bicyclo<2.2.1>heptan-2-exo-ol 
• 38108-56-4 (1R,4R)-exo-3-benzyl-exo-1,7,7-trimethyl-bicyclo<2.2.1>heptan-2-ol 
• 24797-59-9 (+)-(1R,4R)-exo-3-benzylbornanone 

Downstream Products

• 24797-59-9 (+)-(1R,4R)-endo-3-benzylbornan-2-one 

Relevant articles and documents

Synthesis and structural elucidation of novel camphor-derived thioureas

Nine novel (+)-camphor-derived thioureas have been prepared. 3-((Dimethylamino)methylene)camphor (2) served as the common precursor for the preparation of both, 2-thiourea 15-20 and 3-thiourea functionalized camphor derivatives 6, 7/7′, respectively. Starting from 2, the latter were prepared in two or three steps whereas the former in five steps, respectively. Configuration of all novel compounds has been meticulously determined using NMR techniques and/or single crystal X-ray crystallography. Copyright

THE OCTANT RULE XXIII. ANTIOCTANT EFFECTS IN γ,δ-UNSATURATED KETONES

The exo and endo α-benzyl derivatives (1 and 2. respectively) of (+)-camphor have been synthesized and are found to exert a strong influence on the circular dichroism n?* Cotton effects: 1: Δε301max -0.36 (n-heptane) and 2: Δε302max +3.22, relative to camphor: Δε304max + 1.8 (n-heptane).Evidence for electric dipole transition moment coupling in these γ,δ-unsaturated systems is found in the n?* UV: 1: ε291max 84 (n-heptane) and 2: ε285max 303, relative to camphor: ε290max 25.