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382607-99-0

PtCl2(C5H8(P(OC6H5)2)2) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 382607-99-0 Structure

  • Basic information

    1. Product Name: PtCl2(C5H8(P(OC6H5)2)2)
    2. Synonyms:
    3. CAS NO:382607-99-0
    4. Molecular Formula:
    5. Molecular Weight: 768.472
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 382607-99-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: PtCl2(C5H8(P(OC6H5)2)2)(CAS DataBase Reference)
    10. NIST Chemistry Reference: PtCl2(C5H8(P(OC6H5)2)2)(382607-99-0)
    11. EPA Substance Registry System: PtCl2(C5H8(P(OC6H5)2)2)(382607-99-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 382607-99-0(Hazardous Substances Data)

382607-99-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 382607-99-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,8,2,6,0 and 7 respectively; the second part has 2 digits, 9 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 382607-99:
(8*3)+(7*8)+(6*2)+(5*6)+(4*0)+(3*7)+(2*9)+(1*9)=170
170 % 10 = 0
So 382607-99-0 is a valid CAS Registry Number.

382607-99-0Upstream product

382607-99-0Downstream Products

382607-99-0Relevant articles and documents

Chirale Bisphosphane VI. Chelatkomplexe von Platin(II) mit racemischen und optisch reinen trans-Cyclopentan-1,2-diyl-bis(phosphonigsaeurediester)- und trans-Cyclopentan-1,2-diyl-bis(phosphonigsaeurediamid)-Liganden: Synthesen, Strukturen und C-H-Aktivierungsreaktionen1

Dahlenburg, Lutz,Becker, Corinna,Hoeck, Juergen,Mertel, Stefan

, p. 155 - 166 (1998)

New bidentate ligands of the type C5H8(PX2)2 [PX2=P(OMe)2 (2), P(OPh)2 (3), P[OCH(Me)Et-(S)]2 (4), P[OC6H9(Me)Pri-(1R)]2 (5), P[OCH(CO2Pri)-(R)-]2 (6), P[N(CH2)5-cyclo]2 (7), P[N(CH2)4O-cyclo]2 (8)] were prepared from rac-C5H8(PCl2)2 (1) and the corresponding alcohols, diols, and secondary amines. These reacted with [(1,5-C8H12)Pt(CH2CMe3)2] to give Pt(II) derivatives, [C5H8{P(OR)2}2Pt(CH2CMe3)2] [P(OR)2=P(OMe)2 (9), P(OPh)2 (10), P[OCH(Me)Et-(S)]2 (11), P[OC6H9(Me)Pri-(1R)]2 (12), P[OCH(CO2Pri)-(R)-]2 (13)] and [C5H8{P(NR2)2}2Pt(CH 2CMe3)2] [P(NR2)2=P[N(CH2)5-cyclo]2 (14), P[N(CH2)4O-cyclo]2 (15)], respectively. Controlled acidolysis of 9, 10, 12, and 13 yielded the chloro neopentyls [C5H8{P(OR)2}2Pt(Cl)CH2CM e3] [(P(OR)2=P(OMe)2 (16), P(OPh)2 (17), P[OC6H9(Me)Pri-(1R)]2 (18), P[OCH(CO2Pri)-(R)-]2 (19)]. Their P-N-bonded analogues [C5H8{P(NR2)2}2Pt(Cl)CH2CMe3] [P(NR2)2=P[N(CH2)5-cyclo]2 (20), P[N(CH2)4O-cyclo]2 (21)] were obtained by substituting the diene ligand of [(1,5-C8H12)Pt(Cl)CH2CMe3] for bidentates 7 and 8. Treatment of 20 and 21 with Na[BH(OMe)3] in THF provided neopentyl hydrides, [C5H8{P(NR2)2}2Pt(H)CH2CMe3] [P(NR2)2=P[N(CH2)5-cyclo]2 (23), P[N(CH2)4O-cyclo]2 (24)], which exhibited similar inertness toward reductive elimination at temperatures below 60°C as did the previously investigated P-C-substituted derivative [C5H8{P(C6H11-cyclo)2}2Pt(H)CH2CMe3]. The crystal structures of [(1S,2S)-C5H8{P[OC6H9(Me)Pri-(1R)]2}2Pt(CH2CMe3)2] , (1S,2S)-12, [C5H8{P[N(CH2)4O-cyclo]2} 2Pt(CH2CMe3)2], 15, [(1S,2S)-C5H8{P[OC6H9(Me)Pri-(1R)]2}2Pt(Cl)CH2CMe3], (1S,2S)-18, and also of [C5H8{P(OPh)2}PtCl2], 22, were determined by X-ray diffraction.

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