38308-09-7Relevant academic research and scientific papers
A COMPLETELY STEREOSELECTIVE INTRAMOLECULAR DIELS-ALDER REACTION IN THE SUBSTITUTED CYCLOHEXANOL SERIES
Alexakis, A.,Jachiet, D.,Toupet, L.
, p. 6203 - 6210 (2007/10/02)
Substituted dienyl cyclohexanols, obtained through opening of cyclohexene oxide by dienyl aluminium reagents, are easily esterified with acryloyl, crotonyl or methacryloyl chloride or with maleic anhydride.These esters undergo a completely stereoselective Lewis acid catalyzed Diels-Alder reaction.The obtained product were characterized by X-ray crystallography.
