38313-03-0Relevant academic research and scientific papers
Effects of Silver Carbonate and p-Nitrobenzoic Acid for Accelerating Palladium-Catalyzed Allylic C-H Acyloxylation
Skhiri, Aymen,Nagae, Haruki,Tsurugi, Hayato,Seki, Masahiko,Mashima, Kazushi
supporting information, p. 7044 - 7048 (2021/09/13)
An allylic C-H acyloxylation of terminal alkenes with 4-nitrobenzoic acid was assisted by a bidentate-sulfoxide-ligated palladium catalyst combined with 1,4-benzoquinone and Ag2CO3 under mild reaction conditions. The catalytic activity was remarkably enhanced by Ag2CO3 as an additive and 4-nitrobenzoic acid as a carboxylate source; both components were essential to exhibiting high catalytic activity, high branch selectivity, and a wide substrate scope with low loading of the palladium catalyst. Branch-selective allylic acyloxylation of ethyl 7-octenoate (1a) gave the product which was led to ethyl 6,8-dihydroxyoctanoate (5), a useful synthetic intermediate of (R)-α-lipoic acid.
Solvolysis of 2-Alkenyl-2-cyclohexenyl p-Nitrobenzoates
Ladika, Mladen,Sunko, Dionis E.
, p. 4544 - 4548 (2007/10/02)
In an attempt to study possible ?-participation in allyl derivatives, 2-alkenyl-3-methyl-2-cyclohexenyl p-nitrobenzoates 6 and 7 were solvolyzed in 97 wt percent trifluoroethanol and 80 vol percent ethanol.These esters show in both solvents a solvolysis r
