38328-82-4Relevant academic research and scientific papers
Hypervalent silicon hydrides: evidence of their intermediacy in the reaction of optically active 1-NpPhMeSiH(D) with hydrides
Brefort, J. L.,Corriu, R.,Guerin, C.,Henner, B.
, p. 9 - 16 (1989)
Racemisation of optically active 1-NpPhMeSi*H(D) takes place rapidly in the presence of hydrides (KH, LiAlH4, or LiAlD4) in THF at room temperature.Under more drastic conditions, i.e. 50 deg C for 24 h, (+)-1-NpPhMeSiH gave the racemic (+/-)-1-
