3839-86-9

Upstream product

• 5194-51-4 (2E,4E)-hexa-2,4-diene 
• 118622-96-1 N-(4-bromophenylaminothio)phthalimide 
• 5194-50-3 (E,Z)-2,4-hexadiene 
• 26516-62-1 N-sulphinyl-p-bromoaniline 
• 106-40-1 4-bromo-aniline 
• 136123-50-7 C₁₃H₇BrF₁₃NOS 
• 63911-87-5 N-(trimethylsilyl)-4-bromoaniline 

Downstream Products

• 60-29-7 diethyl ether 
• 70-29-1 diethyl sulphide 
• 106-40-1 4-bromo-aniline 
• 57139-16-9 2,5-bis-(4-bromo-phenyl)-1-(4-bromo-phenylimino)-1λ⁴-[1,2,5]thiadiazolidine-3,4-dione 

Relevant academic research and scientific papers

REACTIONS OF α,α,ω-TRIHYDROPOLYFLUOROALKOXYTRIFLUOROSULFURANES WITH PRIMARY AMINES AND AMIDES

α,α,ω-Trihydropolyfluoroalkoxytrifluorosulfuranes react with primary amides or their N,N'-di(trimethylsilyl) derivatives to form acid fluoride derivatives of N-substituted polyfluoroalkyliminosulfurous acids.The thermal stability of these products depends

THE STEREOCHEMICAL OUTCOME OF DIENE ADDITIONS TO THIONITROSOARENES (ArN=S)

Thionitrosoarenes (ArN=S) react efficiently with (E,E)- and (E,Z)-hexadienes to yield 1,2-thiazine adducts in which the stereochemistry of the diene is retained.

SOME KINETIC ASPECTS OF THE ALCOHOLYSIS OF N,N'-DIARYLSULPHURDIIMIDES

Kinetic determinations (at 22 deg C) show that the ethanolysis of N,N'-diarylsulphurdiimides 1 - 9, catalysed by anhydrous copper(II) chloride, obeys a first-order rate law with respect to N,N'-diarylsulphurdiimide.The logarithm of the observed first-order rate constants (at the same concentration of the catalyst) can be correlated with the Hammett ? substituent constants.The ethanolysis rate of 1 - 9 is increased by the electron-withdrawing effect of the substituents linked to the aromatic rings of N,N'-diarylsulphurdiimide.The observed first-order rate constant of the CuCl2-catalysed ethanolysis of N,N'-bis(p-tolyl)sulphurdiimide, 3, is directly proportional to the catalyst concentration: kobs = k2.The second-order rate constants, k2, of the alcoholysis of 3 were measured in four alcohols different from ethanol.These constants seem to be a function of the polarity of the reaction medium and of the steric hindrance of the alcohol.Finally, it was ascertained that the catalysing power of CuCl2 in the ethanolysis of 3 is higher than that of NiCl2 and CoCl2.