384-95-2Relevant academic research and scientific papers
Fluoroanalogs of DDT: Superacidic BF3-H2O catalyzed facile synthesis of 1,1,1-trifluoro-2,2-diarylethanes and 1,1-difluoro-2,2- diarylethanes
Prakash, G. K. Surya,Paknia, Farzaneh,Mathew, Thomas,Mloston, Gzregorz,Joschek, Jens P.,Olah, George A.
supporting information; experimental part, p. 4128 - 4131 (2011/10/04)
The one-pot synthesis of 1,1,1-trifluoro- and 1,1-difluoro-2,2- diarylethanes from arenes and fluorinated hemiacetals in the BF 3-H2O system is described. The reaction is simple, clean, and convenient, eliminating the use of organic
Condensations of aryl trifluoromethyl ketones with arenes in acidic media
O'Connor, Matthew J.,Boblak, Kenneth N.,Spitzer, Ashley D.,Gucciardo, Peter A.,Baumann, Andrew M.,Peter, Joshua W.,Chen, Connie Y.,Peter, Ronald,Mitton, Adam A.,Klumpp, Douglas A.
scheme or table, p. 4984 - 4987 (2011/02/21)
The chemistry of trifluoromethyl ketones has been studied. The work examines the condensation reactions of trifluoromethyl ketones with arenes in the superacid, including both synthetic and mechanistic aspects.
