38417-53-7Relevant academic research and scientific papers
Visible light catalyzed methylsulfoxidation of (het)aryl diazonium salts using DMSO
Pramanik, Mukund M. D.,Rastogi, Namrata
supporting information, p. 8557 - 8560 (2016/07/13)
The visible light catalyzed methylsulfoxidation of (het)aryl diazonium salts using DMSO is illustrated. This is the first example of DMSO being used as the source of the methylsulfinyl group. The procedure tolerates a wide range of functional groups on (het)aryl diazonium salts and provides aryl methyl sulfoxides in excellent yields under mild reaction conditions.
Generation of peracetic acid on aging of perborate solution in acetic acid: Kinetics of oxidation of organic sulfides
Karunakaran,Sheerin,Palanisamy
, p. 398 - 400 (2007/10/03)
Perborate in acetic acid generates peracetic acid on aging and affords H2O2 in ethylene glycol; the oxidations of dialkyl, alkyl aryl and diaryl sulfides in ethylene glycol-acetic acid are second order and uncatalysed by acid, and fo
On the mechanism of the perborate oxidation of organic sulfides in glacial acetic acid
Karunakaran, Chockalingam,Kamalam, Ramasamy
, p. 3261 - 3263 (2007/10/03)
Perborate solution in glacial acetic acid generates peracetic acid on aging, and the peracetic acid oxidation of organic sulfides is fast. The oxidation with fresh solutions of perborate in acetic acid is smooth and is second order, uncatalyzed by acid; h
