384333-58-8

Basic information

• Product Name: (Z)-4,4-dimethyl-3-phenylpent-2-en-1-ol
• Synonyms: (Z)-4,4-dimethyl-3-phenylpent-2-en-1-ol
• CAS NO: 384333-58-8
• Molecular Weight: 190.285
• Mol File: 384333-58-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (Z)-4,4-dimethyl-3-phenylpent-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-4,4-dimethyl-3-phenylpent-2-en-1-ol(384333-58-8)
• EPA Substance Registry System: (Z)-4,4-dimethyl-3-phenylpent-2-en-1-ol(384333-58-8)

Safety Data

• Hazardous Substances Data: 384333-58-8(Hazardous Substances Data)

Upstream product

• 77920-99-1 (Z)-ethyl 4,4-dimethyl-3-phenylpent-2-enoate 
• 872284-55-4 ethyl (E)-4,4-dimethyl-3-phenyl-2-pentenoate 

Downstream Products

• 137623-80-4 (3S)-4,4-dimethyl-3-phenylpentanal 

Relevant articles and documents

Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols Using MaxPHOX Ligands: Experimental and Theoretical Study

The asymmetric isomerization of primary allylic alcohols to chiral aldehydes using iridium-catalysts bearing P,N-MaxPHOX ligands has been studied. These catalysts can be fine-tuned as they present three different stereogenic centers to modulate both the reactivity and enantioselectivity of a family of different substrates. The experimental part is supported by a DFT study of the reaction mechanism, which provides new insights into the key steps of this transformation.