38451-63-7Relevant academic research and scientific papers
Oxidation of o-Methoxyphenols with a Hypervalent Iodine Reagent: Improved Synthesis of Asatone and Demethoxyasatone
Kuerti, Laszlo,Szilagyi, Laszlo,Antus, Sandor,Nogradi, Mihaly
, p. 2579 - 2582 (2007/10/03)
Oxidation of the 2-methoxyphenols 1c-f with phenyliodonium(III) diacetate (PIDA) in methanol resulted in the formation of the cyclohexa-2,4-dienones 4c-f, which dimerized spontaneously to a single product (5c-f) in each case. Using this method the synthes
Anodic Oxidation of 4-Allyl-2,6-dimethoxyphenol and Related Compounds: Syntheses of Asatone and Related Neolignans
Nishiyama, Atsuko,Eto, Hideo,Terada, Yukimasa,Iguchi, Masanobu,Yamamura, Shosuke
, p. 2820 - 2833 (2007/10/02)
4-Allyl-2,6-dimethoxyphenol and related compounds have been subjected to anodic oxidation to afford a number of oxidation products including asatone-type neolignans, heterotropanone-type compounds and arylpropanoids.Furthermore, the formation processes of these oxidation products are shown to involve both radical and cationic reactions which are dependent upon the applied potentials, solvent media and substituents on the aromatic ring.Keywords - allylphenol; neolignan; electrochemical oxidation; Diels-Alder reaction; biomimetic synthesis
