38454-62-5

Basic information

• Product Name: Benzene, 1-methoxy-4-[(1Z)-1-methyl-1-propenyl]-
• CAS NO: 38454-62-5
• Molecular Formula: C11H14O
• Molecular Weight: 162.232
• Mol File: 38454-62-5.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-4-[(1Z)-1-methyl-1-propenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-[(1Z)-1-methyl-1-propenyl]-(38454-62-5)
• EPA Substance Registry System: Benzene, 1-methoxy-4-[(1Z)-1-methyl-1-propenyl]-(38454-62-5)

Safety Data

• Hazardous Substances Data: 38454-62-5(Hazardous Substances Data)

Upstream product

• 4736-60-1 ethyltriphenylphosphonium iodide 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 51431-73-3 1-(but-2-en-2-yl)-4-methoxybenzene 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 78-93-3 butanone 
• 10467-10-4 ethylmagnesium iodide 
• 121-97-1 4-Methoxypropiophenone 
• 52178-73-1 1-(2,2-dibromo-1-methylcyclopropyl)-4-methoxybenzene 
• 21758-19-0 4-(but-1-en-2-yl)anisole 
• 191725-57-2 1-methoxy-4-(1-methoxyprop-1-en-2-yl)benzene 
• 1712-69-2 1-isopropenyl-4-methoxybenzene 
• 925-90-6 ethylmagnesium bromide 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 4031-16-7 N'-2-butanylidene-4-methylbenzenesulfonohydrazine 

Downstream Products

• 38454-63-6 Z-2-(4-methoxyphenyl)-2-butene 
• 21758-19-0 4-(but-1-en-2-yl)anisole 
• 120695-61-6 cis-1-cyano-2-(4-methoxyphenyl)-1-propene 
• 120695-60-5 trans-1-cyano-2-(4-methoxyphenyl)-1-propene 
• 51431-74-4 p-(2,2-dichloro-1,3-dimethylcyclopropyl)anisole 
• 4917-90-2 1-sec-butyl-4-methoxybenzene 
• 4132-48-3 1-methoxy-4-(1-methylethyl)benzene 
• 35144-34-4 erythro-3-(4-methoxyphenyl)butan-2-ol 

Relevant articles and documents

A catalytic diastereoselective formal [5+2] cycloaddition approach to azepino[1,2-a]indoles: Putative donor-acceptor cyclobutanes as reactive intermediates

A catalytic formal [5+2] cycloaddition approach to the diastereoselective synthesis of azepino[1,2-a]indoles is reported. The reaction presumably proceeds through a Lewis acid catalyzed formal [2+2] cycloaddition of an alkene with an N-indolyl alkylidene b-amide ester to form a donor-acceptor cyclobutane intermediate, which subsequently undergoes an intramolecular ring-opening cyclization. Azepine products are formed in up to 92% yield with high degrees of diastereose-lectivity (up to 34:1 d.r.).

Iron Catalyzed Isomerization of α-Alkyl Styrenes to Access Trisubstituted Alkenes

Stereoselective isomerization of α-alkyl styrenes is accomplished using a new iron catalyst supported by phosphine-pyridine-oxazoline (PPO) ligand. The protocol provides an atom-efficient and operationally simple approach to trisubstituted alkenes in high

Cobalt-Catalyzed Migrational Isomerization of Styrenes

An efficient cobalt-catalyzed migrational isomerization of styrenes was developed using the thiazoline iminopyridine (TIP) ligand. This reaction is operationally simple and atom-economical using readily available starting materials to access trisubstituted alkenes. Even when using a 0.1 mol % catalyst loading, the reaction could be conducted in neat and completed in 1 h with excellent conversion and high E stereoselectivity.