4031-16-7Relevant academic research and scientific papers
The microwave-assisted ortho-alkylation of azine N-oxides with N-tosylhydrazones catalyzed by copper(i) iodide
Jha, Abadh Kishor,Jain, Nidhi
supporting information, p. 1831 - 1834 (2016/02/05)
A copper catalyzed regioselective cross-coupling of N-tosylhydrazones with azine N-oxides to yield ortho-alkylated products in moderate to good yields is reported. The reaction is facilitated by microwave, takes place without any ligand, and uses inexpensive copper(i) iodide as the catalyst.
The benzyne Fischer-indole reaction
McAusland, Donald,Seo, Sangwon,Pintori, Didier G.,Finlayson, Jonathan,Greaney, Michael F.
supporting information; experimental part, p. 3667 - 3669 (2011/09/16)
A new approach to the Fischer-indole synthesis is reported that uses the reactive intermediate benzyne. The addition of N-tosyl hydrazones to arynes, generated through fluoride activation of 2-(trimethylsilyl)phenyl triflate precursors, leads to efficient
Tosylhydrazines by the Reduction of Tosylhydrazones with Triethylsilane in Trifluoroacetic Acid
Wu, Pei-Lin,Peng, Shao-Yu,Magrath, Joe
, p. 249 - 252 (2007/10/03)
Tosylhydrazines were easily prepared by the reduction of tosylhydrazones with triethylsilane in the presence of trifluoroacetic acid.
