3846-07-9Relevant academic research and scientific papers
Synthetic studies on the 1,6-methano[10]annulene skeleton: A new route that provides derivatives substituted at the bridge and on the annulene ring
Barrett, David G.,Liang, Gui-Bai,McQuade, D. Tyler,Desper, John M.,Schladetzky, Kurt D.,Gellman, Samuel H.
, p. 10525 - 10532 (2007/10/02)
A new synthetic route to the 1,6-methano[10]annulene skeleton has been developed. The key step in this route is the semi-benzylic Favorskii rearrangement of a [4.4.2]propellane to a [4.4.1]propellane. The methodology discussed here provides access to 1,6-
