38477-80-4

Basic information

• Product Name: Benzene, 1-methoxy-2-(2-propenylthio)-
• Synonyms: Benzene,1-methoxy-2-(2-propenylthio);allyl o-methoxyphenyl thioether;2-methoxyphenyl allyl sulfide;1-methoxy-2-(2-propenylthio)benzene;o-methoxyphenyl allyl sulfide
• CAS NO: 38477-80-4
• Molecular Formula: C10H12OS
• Molecular Weight: 180.271
• Mol File: 38477-80-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-2-(2-propenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-2-(2-propenylthio)-(38477-80-4)
• EPA Substance Registry System: Benzene, 1-methoxy-2-(2-propenylthio)-(38477-80-4)

Safety Data

• Hazardous Substances Data: 38477-80-4(Hazardous Substances Data)

Upstream product

• 7217-59-6 2-Methoxybenzenethiol 
• 106-95-6 allyl bromide 
• 13920-94-0 bis(2-methoxyphenyl)disulfide 

Downstream Products

• 1064703-89-4 C₁₀H₁₁⁽²⁾HOS 
• 83876-14-6 (3β,20S,23Z)-3,20-Dihydroxy-21-methoxy-24-<(2-methoxyphenyl)thio>-24-(trimethylsilyl)-5β-chol-23-ene 
• 83897-12-5 S-(2-Methoxyphenyl) (3β,20S,22E)-3,20-Dihydroxy-21-methoxy-5β-chol-22-ene-24-thioate 
• 113943-96-7 cis 3-(3,4-dichlorophenyl)-3-<(1H-imidazol-1-yl)methyl>-5-<<(2-methoxyphenyl)thio>methyl>-2-methylisoxazolidine 
• 83862-67-3 1-<(2-Methoxyphenyl)thio>-1-(trimethylsilyl)-2-propene 

Relevant articles and documents

Synthesis of sulfimides and N-Allyl-N-(thio)amides by Ru(II)catalyzed nitrene transfer reactions of N-acyloxyamides

The N-acyloxyamides were employed as effective N-acyl nitrene precursors in reactions with thioethers under the catalysis of a commercially available Ru(II) complex, from which a variety of sulfimides were synthesized efficiently and mildly. If an allyl group is contained in the thioether precursor, the [2,3]-sigmatropic rearrangement of the sulfimide occurs simultaneously and the N-allyl-N-(thio)amides were obtained as the final products. Preliminary mechanistic studies indicated that the Ru-nitrenoid species should be a key intermediate in the transformation.

Selective O-deallylation of o-allyloxyanisoles

o-Allyloxyanisoles are selectively and easily deallylated by treatment with sec- or tert-butyllithium at low temperature. The reaction is proposed to proceed through a tandem intermolecular carbolithiation-β;-elimination process, which can also be considered an SN2′ attack of the organolithium on the allyl ether.

A synthesis of 3β hydroxy 5β,14α bufa 20,22 dienolide from deoxycorticosterone

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