385443-70-9

Upstream product

• 385443-52-7 methyl (2R,3S,4R,5S,6S,7R,8E,10S)-11-[(1,1-dimethylethyl)dimethylsilyloxy]-3,5-(4-methoxybenzylidenedioxy)-2,7-bis(methoxymethoxy)-4,6,8,10-tetramethyl-8-undecenoate 
• 385443-53-8 methyl (2R,3S,4S,5R,6S,7R,8E,10S)-9-[(1,1-dimethylethyl)dimethylsilyloxy]-2,3-dihydroxy-5-(4-methoxybenzyloxy)-7-methoxymethoxy-4,6,8,10-tetramethyl-8-undecenoate 
• 385443-68-5 methyl (2R,3S,4R,5S,6S,7R,8E,10S)-11-[(1,1-dimethylethyl)dimethylsilyloxy]-2-hydroxy-3,5-(4-methoxybenzylidenedioxy)-7-methoxymethoxy-4,6,8,10-tetramethyl-8-undecenoate 
• 385443-67-4 methyl (2E,4S,5R,6S,7R,8E,10S)-11-[(1,1-dimethylethyl)dimethylsilyloxy]-5-(4-methoxybenzyloxy)-7-methoxymethoxy-4,6,8,10-tetramethyl-8-undecenoate 
• 385443-57-2 (2S,3R,4S,5R,6E,8S)-9-[(1,1-dimethylethyl)dimethylsilyloxy]-3-(4-methoxybenzyloxy)-5-methoxymethoxy-2,4,6,8-tetramethyl-6-nonenol 
• 385443-62-9 (2S,4R,5R,6E,8S)-9-[(1,1-dimethylethyl)dimethylsilyloxy]-5-hydroxy-1-(4-methoxybenzyloxy)-2,4,6,8-tetramethyl-6-nonen-3-one 
• 385443-54-9 (2S,3R,4S,5R,6E,8S)-9-[(1,1-dimethylethyl)dimethylsilyloxy]-1-(4-methoxybenzyloxy)-2,4,6,8-tetramethyl-6-nonene-3,5-diol 
• 385443-66-3 (2R,3S,4R,5R,6E,8S)-9-[(1,1-dimethylethyl)dimethylsilyloxy]-3-(4-methoxybenzyloxy)-5-methoxymethoxy-2,4,6,8-tetramethyl-6-nonenal 
• 385443-65-2 (2S,3R,4S,5R,6E,8S)-9-[(1,1-dimethylethyl)dimethylsilyloxy]-1,3-(4-methoxybenzylidenedioxy)-5-methoxymethoxy-2,4,6,8-tetramethyl-6-nonene 
• 385443-64-1 (2S,3R,4R,5R,6E,8S)-9-[(1,1-dimethylethyl)dimethylsilyloxy]-5-hydroxy-1,3-(4-methoxybenzylidenedioxy)-2,4,6,8-tetramethyl-6-nonene 
• 385443-56-1 ethyl (2E,4S)-5-[(1,1-dimethylethyl)dimethylsilyloxy]-2,4-dimethylpentenoate 
• 385443-61-8 (2E,4S)-5-[(1,1-dimethylethyl)dimethylsilyloxy]-2,4-dimethylpentenol 
• 385443-55-0 (2E,4S)-5-[(1,1-dimethylethyl)dimethylsilyloxy]-2,4-dimethylpentanal 
• 185203-71-8 methyl (S)-N-methyl-N-methoxy-3-(4-methoxybenzyloxy)-2-methylpropanoate 

Downstream Products

• 385443-71-0 methyl (2R,3S,4R,5S,6S,7R,8E,10S)-11-hydroxy-3,5-(4-methoxybenzylidenedioxy)-2,7-bis(methoxymethoxy)-4,6,8,10-tetramethyl-8-dodecenoate 

Relevant academic research and scientific papers

Stereoselective synthesis of the C(1)-C(12) fragments of tedanolides - Application of a syn-selective tin(II)-mediated aldol reaction and a convertible methoxybenzyl protecting group

Stereoselective synthesis of two C(1)-C(12) fragments, 3 and 4, of antitumor agents tedanolide (1) and 13-deoxytedanolide (2) was achieved by means of several regio- and/or stereoselective reactions. Ethyl ketone 14 was synthesized from methyl (S)-3-hydro