385443-75-4

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 385443-59-4 methyl (2R,3S,4S,5R,6S,7R,8E,10S)-7,11-bis[(1,1-dimethylethyl)dimethylsilyloxy]-2,3-dihydroxy-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-8-undecenoate 
• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 
• 385443-74-3 methyl (2E,4S,5R,6S,7R,8E,10S)-7,11-bis[(1,1-dimethylethyl)dimethylsilyloxy]-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-2,8-undecadienoate 
• 385443-58-3 (2S,3R,4S,5R,6E,8S)-5,9-bis[(1,1-dimethylethyl)dimethylsilyloxy]-3-(4-methoxybenzyloxy)-2,4,6,8-tetramethyl-6-nonenol 
• 385443-72-1 (2S,3R,4S,5R,6E,8S)-5,9-bis[(1,1-dimethylethyl)dimethylsilyloxy]-1,3-(4-methoxybenzylidenedioxy)-2,4,6,8-tetramethyl-6-nonene 
• 385443-73-2 (2R,3S,4S,5R,6E,8S)-5,9-bis[(1,1-dimethylethyl)dimethylsilyloxy]-3-(4-methoxybenzyloxy)-2,4,6,8-tetramethyl-6-nonenal 
• 385443-62-9 (2S,4R,5R,6E,8S)-9-[(1,1-dimethylethyl)dimethylsilyloxy]-5-hydroxy-1-(4-methoxybenzyloxy)-2,4,6,8-tetramethyl-6-nonen-3-one 
• 385443-54-9 (2S,3R,4S,5R,6E,8S)-9-[(1,1-dimethylethyl)dimethylsilyloxy]-1-(4-methoxybenzyloxy)-2,4,6,8-tetramethyl-6-nonene-3,5-diol 
• 385443-64-1 (2S,3R,4R,5R,6E,8S)-9-[(1,1-dimethylethyl)dimethylsilyloxy]-5-hydroxy-1,3-(4-methoxybenzylidenedioxy)-2,4,6,8-tetramethyl-6-nonene 
• 385443-56-1 ethyl (2E,4S)-5-[(1,1-dimethylethyl)dimethylsilyloxy]-2,4-dimethylpentenoate 
• 385443-61-8 (2E,4S)-5-[(1,1-dimethylethyl)dimethylsilyloxy]-2,4-dimethylpentenol 
• 385443-55-0 (2E,4S)-5-[(1,1-dimethylethyl)dimethylsilyloxy]-2,4-dimethylpentanal 
• 185203-71-8 methyl (S)-N-methyl-N-methoxy-3-(4-methoxybenzyloxy)-2-methylpropanoate 

Downstream Products

• 385443-76-5 methyl (2R,3S,4R,5R,6S,7R,8E,10S)-2,7-bis[(1,1-dimethylethyl)dimethylsilyloxy]-11-hydroxy-3-methoxy-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-8-undecenoate 
• 385443-78-7 methyl (2R,3S,4R,5R,6S,7R,8E,10S)-2,7-bis[(1,1-dimethylethyl)dimethylsilyloxy]-11-hydroxy-3-methoxy-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-8-dodecenoate 
• 385443-77-6 methyl (2R,3S,4R,5R,6S,7R,8E,10S)-2,7-bis[(1,1-dimethylethyl)dimethylsilyloxy]-3-methoxy-5-(4-methoxybenzyloxy)-11-oxo-4,6,8,10-tetramethyl-8-undecenoate 
• 385443-60-7 methyl (2R,3S,4R,5R,6S,7R,8E,10S)-2,7,11-tris[(1,1-dimethylethyl)dimethylsilyloxy]-3-methoxy-5-(4-methoxybenzyloxy)-4,6,8,10-tetramethyl-8-undecenoate 

Relevant academic research and scientific papers

Stereoselective synthesis of the C(1)-C(12) fragments of tedanolides - Application of a syn-selective tin(II)-mediated aldol reaction and a convertible methoxybenzyl protecting group

Stereoselective synthesis of two C(1)-C(12) fragments, 3 and 4, of antitumor agents tedanolide (1) and 13-deoxytedanolide (2) was achieved by means of several regio- and/or stereoselective reactions. Ethyl ketone 14 was synthesized from methyl (S)-3-hydro