38575-63-2

Basic information

• Product Name: methyl 1,4,5,6,7,7-hexabromobicyclo[2.2.1]hept-5-ene-2-carboxylate
• CAS NO: 38575-63-2
• Molecular Formula: C₉H₆Br₆O₂
• Molecular Weight: 625.5667
• Mol File: 38575-63-2.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 443.3°C at 760 mmHg
• Flash Point: 221.9°C
• Density: 3.033g/cm³
• Vapor Pressure: 4.67E-08mmHg at 25°C
• Refractive Index: 1.789
• CAS DataBase Reference: methyl 1,4,5,6,7,7-hexabromobicyclo[2.2.1]hept-5-ene-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 1,4,5,6,7,7-hexabromobicyclo[2.2.1]hept-5-ene-2-carboxylate(38575-63-2)
• EPA Substance Registry System: methyl 1,4,5,6,7,7-hexabromobicyclo[2.2.1]hept-5-ene-2-carboxylate(38575-63-2)

Safety Data

• Hazardous Substances Data: 38575-63-2(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 446300-54-5 (-)-menthyl 1,2,3,4,7,7-hexabromobicyclo[2.2.1]hept-2-ene-5-carboxylate 
• 67-56-1 methanol 
• 102516-24-5 1,4,5,6,7,7-hexabromobicyclo<2.2.1>hept-5-ene-2-carbonyl chloride 
• 14362-06-2 1,4,5,6,7,7-hexabromobicyclo<2.2.1>hept-5-ene-2-carboxylic acid 
• 14310-17-9 hexabromocyclopenta-1,3-diene 
• 292638-85-8 acrylic acid methyl ester 

Relevant articles and documents

Asymmetric synthesis of chiral norbornenes from polybromocyclopentadienes

Effect of the conditions on the enantiomeric purity, overall yield, and isomeric composition of chiral polybromonorbornene Diels-Alder adducts of polybromocyclopentadienes and (-)-menthyl acrylate was studied. Enantiomerically pure polybromonorbornenecarboxylic acids were obtained by resolution of the corresponding racemates through diastereoisomeric salts with l-ephedrine. The structure of the products was confirmed by the IR and 1H NMR spectra.