385809-10-9

Upstream product

• 527742-93-4 Methanesulfonic acid (1S,3R)-1-(tert-butyl-dimethyl-silanyloxymethyl)-3-methyl-5-phenylsulfanyl-pentyl ester 
• 385809-07-4 [2S,4R]-6-(tert-butyldimethylsilanyloxy)-4-methyl-6-phenylsulfanylhexan-2-ol 
• 527742-94-5 (6R)-6-[(2R)-(4-benzenesulfonyl-2-methylbutyl)]-5,6-dihydro-2H-pyran-2-one 
• 527742-74-1 [3S,5S]-6-(tert-butyldimethylsilanyloxy)-3-methylhexane-1,5-diol 
• 385809-09-6 (6R)-6-[(2R)-(2-methyl-4-phenylsulfanyl-butyl)]-5,6-dihydro-2H-pyran-2-one 
• 385809-06-3 [4R,6S]-6-(tert-butyldimethylsilanyloxymethyl)-4-methyl-tetrahydropyran-2-one 
• 527742-76-3 (2R)-2-[(2R)-(4-benzenesulfonyl-2-methylbutyl)]oxirane 
• 527742-73-0 (6S)-6-(tert-butyldimethylsilanyloxymethyl)-5,6-dihydro-2H-pyran-2-one 
• 385809-08-5 (2R)-2-[(2R)-(2-methyl-4-phenylsullfanyl-butyl)]oxirane 
• 89408-85-5 (S)-6-(hydroxymethyl)-5,6-dihydro-2H-pyran-2-one 
• 38435-08-4 trimethyl 3-(phenylsulfonyl)orthopropionate 
• 385809-11-0 [3R,5S]-[5-(1R,S)-(1-ethoxyallyloxy)-3-methyl-oct-7-ene-1-yl-sulfonyl]benzene 
• 64-17-5 ethanol 

Downstream Products

• 385809-12-1 [2R,6R]-6-[(2R)-(4-benzenesulfonyl-2-methylbutyl)-5,6-dihydro-2H-pyran-2-yl]acetaldehyde 
• 385809-16-5 (2R,6R)-tert-butyl-[2-(6-{4-[(2S)-3-(4-methoxybenzyloxy)-2-methoxymethoxy-propyl]-[(2S)-2-methylpent-4-enyl]}-5,6-dihydro-2H-pyran-2-yl)-ethoxy]-dimethylsilane 
• 527742-78-5 [2R,6R]-6-[(2R)-(4-benzenesulfonyl-2-methylbutyl)-5,6-dihydro-2H-pyran-2-yl]ethanol 
• 385809-13-2 [2R,(2R),6R]-{2-[6-(4-benzenesulfonyl-2-methylbutyl)-5,6-dihydro-2H-pyran-2-yl]ethoxy}-tert-butyldimethylsilane 
• 385809-14-3 (2S,4RS,6R)-4-benzenesulfonyl-7-{(2R,6R)-6-[2-(tert-butyldimethylsilanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-1-(4-methoxybenzyloxy)-6-methylheptan-2-ol 
• 385809-15-4 (2S,4RS,6S)-(2-{(2R,6R)-6-[4-benzenesulfonyl-7-(4-methoxybenzyloxy)-6-methoxymethoxy-2-methylheptyl]-5,6-dihydro-2H-pyran-2-yl}-ethoxy)-tert-butyldimethylsilane 
• 385809-24-5 [(2S),(2S,6S,7E,10S,11S,12E),(2R,6R)]-tert-butyl-(2-{6-[10-(4-methoxybenzyloxy)-6,11-bismethoxymethoxy-2-methyl-13-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylenetrideca-7,12-dienyl]-5,6-dihydro-2H-pyran-2-yl}ethoxy)-dimethylsilane 

Relevant academic research and scientific papers

An intramolecular case of sharpless kinetic resolution: Total synthesis of laulimalide

The microtubule-stabilizing antitumor agent laulimalide (1) has been obtained in by new synthetic route. The carbon skeleton was assembled by means of Julia-Kocienski (C16-C17) and Horner-Wadsworth-Emmons (C21-C22) olefinations. Still-Gennari olefination