38633-12-4Relevant academic research and scientific papers
THE MATRIX EFFECT ON STEREOSELECTIVITY OF OLEFIN CYCLOPROPANATION BY ARYLCARBENE
Tomioka, Hideo,Ozaki, Yasuji,Koyabu, Yasuhiro,Izawa, Yasuji
, p. 1917 - 1920 (1982)
Temperature studies of addition of phenylcarbene to styrene showed that stereoselectivity changed rather dramatically as the reaction phase changed.
NUCLEOPHILIC CHARACTER OF AN ELECTROPHILIC CARBENE. SYNTHESIS OF CYCLOPROPANES BY THERMAL DECOMPOSITION OF 3-CHLORO-3-PHENYLDIAZIRINE
Doyle, Michael P.,Terpstra, Jan W.,Winter, Charles H.
, p. 901 - 904 (2007/10/02)
Chlorophenylcarbene reacts with electrophilic olefins to form cyclopropane products in high yield through proposed ylide intermediates.
HAMMETT-KORRELATION VON PHENYLCHLORCARBEN - TEMPERATURABHAENGIGKEIT, SELEKTIVITAET
Brueck, Wolfgang,Duerr, Heinz
, p. 2175 - 2178 (2007/10/02)
Phenylchlorcarbene 2 reacts as an electrophile as deduced from a Hammett-plot; the ρ-values in the addition reaction with styrenes are clearly temperature dependent.
