38662-39-4 Usage
Uses
Used in Organic Synthesis:
(CH3)3CNSO is used as a source of nucleophilic sulfur for [facilitating reactions involving sulfur] in organic synthesis. Its ability to act as a reagent for the conversion of ketones to epoxides makes it a valuable component in the creation of various chemical compounds.
Used in Solvent Applications:
Trimethylsulfoxonium iodide is used as a solvent for [dissolving a wide range of substances] in chemical reactions. Its solubility in polar solvents allows it to be a versatile option for dissolving both organic and inorganic compounds.
Used in Catalyst Applications:
(CH3)3CNSO is used as a catalyst for [accelerating specific chemical reactions] in certain reactions. Its catalytic properties can help increase the efficiency and speed of these reactions, making it a useful tool in the chemical industry.
Used in Biological Applications:
Trimethylsulfoxonium iodide is used as a potential agent for [various biological applications], although its use in this field is still under study. Its unique chemical properties may offer new possibilities for biological research and applications.
Used in Pharmaceutical Industry:
(CH3)3CNSO is used as a reagent for [the synthesis of pharmaceutical compounds] in the pharmaceutical industry. Its role in converting ketones to epoxides can be particularly useful in the development of new drugs and medications.
Safety Note:
It is important to handle trimethylsulfoxonium iodide with caution as it is highly toxic and irritating. Proper safety measures should be taken to minimize the risk of exposure and ensure the safe use of (CH3)3CNSO in various applications.
Check Digit Verification of cas no
The CAS Registry Mumber 38662-39-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,8,6,6 and 2 respectively; the second part has 2 digits, 3 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 38662-39:
(7*3)+(6*8)+(5*6)+(4*6)+(3*2)+(2*3)+(1*9)=144
144 % 10 = 4
So 38662-39-4 is a valid CAS Registry Number.
InChI:InChI=1/C4H9NOS/c1-4(2,3)5-7-6/h1-3H3
38662-39-4Relevant academic research and scientific papers
A-new synthesis of N-sulfinylamines via β-elimination of chloroform from trichloromethanesulfinamides
Braverman, Samuel,Cherkinsky, Marina
, p. 487 - 490 (2007/10/03)
The synthesis of various N-monosubstituted trichloromethanesulfinamides by two alternative and novel procedures is described. All these compounds have been found to undergo base-induced elimination of chloroform with formation of the corresponding N-sulfinylamines. Reaction proceeds smoothly under mild conditions.
Thiaziridine 1,1-Dioxides
Quast, Helmut,Kees, Frieder
, p. 774 - 786 (2007/10/02)
Experiments towards a 1,3-elimination of hydrogen halides from α-chlorosulfonamides, α-bromosulfonamides, and N-chlorosulfonamides did not yield isolable thiaziridine 1,1-dioxides 4.Therefore, at -78 deg C, the diazoalkanes 10 were allowed to react with N-sulfonylamines 14 generated in situ by hydrogen chloride elimination from sulfamoylchlorides with triethylamine.If the work-up temperature was kept below -30 deg C, from tert-alkyldiazomethanes and tert-alkylsulfamoylchlorides the 2,3-di-tert-alkylthiaziridine 1,1-dioxides 4f - i were obtained in 32 - 47 percent yield.They form colorless, thermally labile crystals.Their structure was based on IR, UV and 1H-NMR spectra as well as on the quantitative thermal decomposition into sulfur dioxide and aldimines.The disubstituted diazomethanes 23 reacted with tert-butylsulfonylamine affording, besides N-tert-butylketimines (the decomposition products of intermediate trisubstituted thiaziridine 1,1-dioxides 21), tert-butylsulfinylamine 25 and ketones 26.The latter products presumably resulted from the cheletropic decomposition of the oxathiiranes 24.
