38676-82-3

Basic information

• Product Name: Gloriogenin
• CAS NO: 38676-82-3
• Molecular Weight: 430.628
• Mol File: 38676-82-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Gloriogenin(CAS DataBase Reference)
• NIST Chemistry Reference: Gloriogenin(38676-82-3)
• EPA Substance Registry System: Gloriogenin(38676-82-3)

Safety Data

• Hazardous Substances Data: 38676-82-3(Hazardous Substances Data)

Upstream product

• 132998-89-1 Chloromaloside C 
• 132998-87-9 diuranthoside B 
• 133024-11-0 Chloromaloside A 
• 137853-58-8 YS-VIII 
• 137853-58-8 YS-VII 
• 38673-27-7 (25R)-5β-spirostan-3,12-dione 
• 4948-48-5 3β-acetoxy-(25R)-5α-spirostan-12-one 
• 79974-44-0 neohecogenin-3-O-β-D-glucopyranoside 
• 6875-60-1 25R-spirost-4-ene-3,12-dione 

Downstream Products

• 126-19-2 sarsasapogenin 
• 1426309-53-6 20-oxo-5α-pregnane-3α,12β-diyl 12-acetate 3-benzoate 
• 467-55-0 hecogenin 

Relevant articles and documents

The NMR studies on two new furostanol saponins from Agave sisalana leaves

The detailed NMR studies and full assignments of the 1H and 13C spectral data for two new furostanol saponins isolated from Agave sisalana leaves are described. Their structures were established using a combination of 1D and 2D NMR techniques including 1H, 13C, 1H-1H COSY, TOCSY, HSQC, HMBC and HSQC-TOCSY, and also FAB-MS spectrometry and chemical methods. The structures were established as (25S)-26-(β-D-glucopyranosyl)-22ξ-hydroxyfurost-12-one-3β-yl-O- α-L-rhamnopyranosyl-(1→4)-β-D-glucopyranosyl-(1→3) -O-[O-β-D-glucopyranosyl-(1→2)]-O-β-D-glucopyranosyl-(1→4) -β-D-galactopyranoside (1) and (25S)-26-(β-D-glucopyranosyl)-22ξ- hydroxyfurost-5-en-12-one-3ξ-yl-O-α-L-rhamnopyranosyl-(1→4) -β-D-glucopyranosyl-(1→3)-O-[O-β-D-glucopyranosyl-(1→2)] -O-β-D-glucopyranosyl-(1→4)-β-D-galactopyranoside (2). Copyright

Synthesis of a new cytotoxic cephalostatin/ritterazine analogue from hecogenin and 22-epi-hippuristanol

A new cephalostatin/ritterazine analogue was prepared from the commercially available hecogenin acetate and the natural cytotoxic steroid 22-epi-hippuristanol. The method involved the reductive dimerization of enaminoketones (condensation of α-aminoketones) and condensation between an enaminoketone and an α-hydroxyketone. The new analogue showed higher cytotoxic activity than the cytotoxic 22-epi-hippuristanol against MDA-MB-231, A-549 and HT-29 cultured tumor cell lines.

STEROIDAL SAPONINS FROM CHLOROPHYTUM MALAYENSE

Four new steroidal saponins, chloromalosides A-D, were isolated from the rhizomes of Chlorophytum malayense.On the basis of detailed chemical and spectroscopic evidence, the structures of chloromalosides A-D were elucidated to be neohecogenin 3-O-β-D-glucopyranosyl(1->2)-3)>-β-D-glucopyranosyl(1->4)-β-D-galactopyranoside, 26-β-D-glucopyranosyl-22-hydroxy-25(S)-5α-furostane-3β,26-diol-3-O-β-D-glucopyranosyl(1->2)-3)>-β-D-glucopyranosyl(1->4)-β-D-galactopyranoside, neohecogenin 3-O-β-D-xylopyranosyl(1->3)-2)>-β-D-glucopyranosyl(1->4)-2)>-β-D-galactopyranoside and neotigogenin 3-O-β-D-xylopyranosyl(1->3)-2)>-β-D-glucopyranosyl(1->4)-2)>-β-D-galactopyranoside, respectively.