38686-57-6Relevant academic research and scientific papers
Photochemically Generated Organometallic Radicals as Reducing Agents
Stiegman, Albert E.,Goldman, Alan S.,Leslie, Douglas B.,Tyler, David R.
, p. 632 - 633 (1984)
Irradiation of metal-metal bonded carbonyl dimers in the presence of appropriate ligands generates a class of intermediates which are powerful reducing agents; Ru3(CO)12, CpMo(CO)3Cl (Cp = cyclopentadienyl), and the ferricyanide ion were reduced in order
CLUSTER CHEMISTRY. XVII. RADICAL ION-INITIATED SYNTHESES OF RUTHENIUM CLUSTER CARBONYLS CONTAINING TERTIARY PHOSPHINES, PHOSPHITES, ARSINES, SbPh3 OR ISOCYANIDES
Bruce, Michael I.,Matisons, Janis G.,Nicholson, Brian K.
, p. 321 - 344 (2007/10/02)
The syntheses of over sixty known and new derivatives of Ru3(CO)12 and H4Ru4(CO)12 by substitution reactions initiated by sodium diphenylketyl are described.The range of ligands studied includes isocyanides, tertiary phosphines and phosphites, tertiary ar
