38793-70-3

Basic information

• Product Name: benzhydryl(tert-butyl)sulfane
• Synonyms: benzhydryl(tert-butyl)sulfane
• CAS NO: 38793-70-3
• Molecular Weight: 256.412
• Mol File: 38793-70-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: benzhydryl(tert-butyl)sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: benzhydryl(tert-butyl)sulfane(38793-70-3)
• EPA Substance Registry System: benzhydryl(tert-butyl)sulfane(38793-70-3)

Safety Data

• Hazardous Substances Data: 38793-70-3(Hazardous Substances Data)

Upstream product

• 2259-30-5 tert-butylmagnesium bromide 
• 1450-31-3 Thiobenzophenon 
• 91-01-0 1,1-Diphenylmethanol 
• 75-66-1 2-methylpropan-2-thiol 
• 119-61-9 benzophenone 
• 110-06-5 di-tert-butyl disulfide 
• 776-74-9 Bromodiphenylmethane 
• 908093-98-1 diazodiphenylmethane 

Downstream Products

• 1224199-14-7 [(4,6-dimethoxy-1,3-phenylene)bis(methanetriyl)]tetrabenzene 
• 70430-05-6 [(2,4-dimethoxyphenyl)methylene]dibenzene 
• 741-74-2 ((2,5-dimethoxyphenyl)methylene)dibenzene 
• 77549-01-0 ((3,4-dimethoxyphenyl)methylene)dibenzene 
• 102751-83-7 ((2,4,6-trimethoxyphenyl)methylene)dibenzene 
• 101-81-5 Diphenylmethane 

Relevant articles and documents

Multimetallic Ir-Sn3-catalyzed substitution reaction of π-activated alcohols with carbon and heteroatom nucleophiles

An atom economic and catalytic substitution reaction of π-activated alcohols by a multimetallic IreSn3 complex has been demonstrated. The multimetallic IreSn3 complex can be easily synthesized from the reaction between [Cp*IrCl2]2 and SnCl2. In presence of as little as 1 mol % of the catalyst three different types of π-activated alcohols, namely benzyl, allyl, and propargyl alcohols, have been successfully transformed into alkylated products using carbon (arenes, heteroarenes, allyltrimethylsilane, and 1,3-dicarbonyls), nitrogen (sulfonamides), oxygen (alcohols), and sulfur (thiols) nucleophiles in very high yields. An electrophilic mechanism is proposed from the Hammett correlation study.

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Grignard reagents react with thiobenzophenone to give mainly the compound resulting from addition of the' organic radical to the sulfur atom. Addition to carbon, double addition both to sulfur and to carbon, and formation of tetraphenylthiiranne are also observed. The stable alkylthiodiphenylmethyl radical has been detected in the reaction medium. A mechanism is proposed to account for the various reactions.