38796-02-0Relevant academic research and scientific papers
Transition metal-catalyzed dehydrogenative germylation of olefins with tri-n-butylgermane
Furukawa, Naoyuki,Kourogi, Noriko,Seki, Yoshio,Kakiuchi, Fumitoshi,Murai, Shinji
, p. 3764 - 3767 (1999)
The catalyzed reaction of an excess of styrene with n-Bu3GeH using several ruthenium and rhodium complexes gave the corresponding vinylgermanes (α-trin-butylgermylstyrene, (Z)-β-tri-n-butylgermylstyrene, and (E)-β-tri-n-butylgermylstyrene), whi
Visible-Light-Initiated Manganese-Catalyzed E-Selective Hydrosilylation and Hydrogermylation of Alkynes
Liang, Hao,Ji, Yun-Xing,Wang, Rui-Han,Zhang, Zhi-Hao,Zhang, Bo
supporting information, p. 2750 - 2754 (2019/04/30)
Manganese-photocatalyzed activation of the Si-H bond in silanes for the hydrosilylation of alkynes has been developed. The mild protocol operates efficiently with high regioselectivity (anti-Markovnikov) and stereoselectivity (Z/E ratio ranges from 92:8 to >99:1), providing a wide range of Z-vinylsilanes in high yields. Moreover, visible-light-induced manganese-catalyzed activation of the Ge-H bond for E-selective alkyne hydrogermylation is reported for the first time.
