388081-99-0

Upstream product

• 994-30-9 triethylsilyl chloride 
• 116060-83-4 (3S,5R)-5-Benzyloxymethyl-3-methyl-dihydro-furan-2-one 
• 14618-80-5 (R)-benzyl glycidol 

Downstream Products

• 388082-03-9 (E)-(4S,6R)-7-Benzyloxy-1-{(2R,3R)-3-[(S)-3-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-butyl]-2-methyl-oxiranyl}-4-methyl-6-triethylsilanyloxy-hept-1-en-3-one 
• 388082-05-1 (E)-(2R,4S)-1-Benzyloxy-7-[(2S,3R,6S)-3-hydroxy-6-(4-methoxy-benzyloxymethyl)-2-methyl-tetrahydro-pyran-2-yl]-4-methyl-hept-6-ene-2,5-diol 
• 388082-06-2 (4S,6R)-7-Benzyloxy-6-hydroxy-1-[(2S,3R,6S)-3-hydroxy-6-(4-methoxy-benzyloxymethyl)-2-methyl-tetrahydro-pyran-2-yl]-4-methyl-heptan-3-one 
• 388082-10-8 (E)-(4S,6R)-7-Benzyloxy-6-hydroxy-1-[(2S,3R,6S)-3-hydroxy-6-(4-methoxy-benzyloxymethyl)-2-methyl-tetrahydro-pyran-2-yl]-4-methyl-hept-1-en-3-one 
• 388082-04-0 (E)-(2R,4S)-1-Benzyloxy-7-{(2R,3R)-3-[(S)-3-hydroxy-4-(4-methoxy-benzyloxy)-butyl]-2-methyl-oxiranyl}-4-methyl-hept-6-ene-2,5-diol 
• 388082-11-9 (E)-(4S,6R)-7-Benzyloxy-1-{(2R,3R)-3-[(S)-3-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-butyl]-2-methyl-oxiranyl}-4-methyl-6-triethylsilanyloxy-hept-1-en-3-ol 

Relevant academic research and scientific papers

Lituarine synthetic studies. An efficient, stereocontrolled construction of the common c(7-19) tricyclic spiroketal fragment.

A highly efficient, stereocontrolled synthesis of (+)-4, the common C(7-19) tricyclic spiroketal fragment of the lituarines A, B, and C (1-3), has been achieved. Highlights of the synthesis include a remarkably facile 6-endo cyclization to access the C(8-