388566-49-2Relevant academic research and scientific papers
Chemistry of dioxacyclanes: VII.1 Synthesis of 1,3-dioxolane derivatives from 3-(2-propenyloxy)propane-1,2-diol and their properties
Kerimov
, p. 542 - 545 (2007/10/03)
2,4-Disubstituted 1,3-dioxolanes were synthesized by reactions of benzaldehyde and its parachloro derivatives, as well as 3-cyclohexenecarboxaldehyde with 3-(2-propenyloxy)-1,2-propanediol. The products were brought into bromination, dichlorocarbene addition, and epoxidation reactions. It is found that when both components of the heterogeneous reaction of dioxolane ring formation have a double bond, the acid catalyst in strongly deactivated.
