388573-73-7Relevant academic research and scientific papers
Substituent dependent regioselective synthesis of pyranopyrandiones and 1,2-teraryls from 2H-pyran-2-ones
Pratap, Ramendra,Sil, Diptesh,Ram, Vishnu Ji
, p. 5025 - 5027 (2005)
The one-pot substituent-directed regioselective synthesis of 1,7-diaryl-2-methyl-4H,5H-pyrano[3,4-c]pyran-4,5-diones 3 as the major and 3,4-diaryl-2-methyl-6-methylsulfanylbenzonitriles 4 as the minor products has been delineated through ring transformation of suitably functionalized 2H-pyran-2-ones 1 with aryl acetones 2. Under similar reaction conditions, 6-aryl-4-sec-amino-2H-pyran-2-ones 5 led, regioselectively, to 3,4-diaryl-2-methyl-6-sec-aminobenzonitriles 6.
Ultrasound-assisted synthesis, photophysical behaviour and single crystal X-ray analysis of highly functionalized prenylarenes
Krishnan, Manjula,Singh, Fateh V
, (2022/02/17)
A rapid, ultrasound assisted base-catalysed metal free synthesis of a novel series linear prenylarenes 17 incorporated with donor-acceptor functionalities is described via carbanion-induced ring transformation of 4-amino-6-aryl-3-cyano-2H-pyran-2-ones 15 with 6-methylhept-5-en-2-one 16 at room temperature with high yields. Notably, all of the synthesised prenylarenes exhibited blue fluorescence in the 406–468 nm region. The stokes shift, optical band gap, and quantum yield of compounds 17a-17l were computed using their absorption and emission spectra. A significant positive solvatochromic effect was observed, and concentration studies revealed the non-aggregating behaviour of synthesised prenylarenes. Single crystal X-ray diffraction analysis of 17d revealed that crystal belongs to triclinic system with P-1 space group with twisted phenyl rings.
Synthesis, spectral characterization and photophysical studies of tetrahydroquinolines
Kennedy, L. John,Singh, Fateh V.,Subashini, C.
, (2020/10/18)
A metal-free, ultrasound-assisted, fast synthesis of fluorescent N-Boc-protected 1,2,3,4–tetrahydroquinolines 9a-p is described through carbanion-induced ring transformation of 6-aryl-2H-pyran-2-ones 7 with tert?butyl 3-oxopiperidine-1-carboxylate 8 under
One-pot synthesis of unsymmetrical biaryls from suitably functionalized 2H-pyran-2-ones through carbanion-induced ring-transformation reactions
Ram,Srivastava,Agarwal,Sharon,Maulik
, p. 1953 - 1959 (2007/10/03)
An innovative synthesis of unsymmetrical biaryls (2,6) with electron-acceptor and electron-donor substituents through carbanion-induced C-C bond formation from 6-aryl-3-cyano-4-methylthio-2H-pyran-2-ones (1) and 4-sec-amino-6-aryl-2H-pyran-2-ones (5), using aliphatic ketones as a source of carbanion, is delineated and illustrated. However, a reaction of pyran-2-ones (1) with aromatic ketones failed to yield any desired product and in lieu a new compound isolated was characterized as the corresponding (4,6-diarylpyran-2-ylidene)acetonitrile (3). The structure of two representative compounds 5h and 6q has been confirmed by single-crystal X-ray diffraction analysis.
