3886-07-5Relevant articles and documents
A method for cleaving an allyl protecting group at the amide nitrogen of peptides by one-pot olefin isomerization-oxidation
Kajihara, Kouki,Arisawa, Mitsuhiro,Shuto, Satoshi
supporting information; experimental part, p. 9494 - 9496 (2009/04/06)
(Chemical Equation Presented) A facile method for N-deallylation at the amide nitrogen of peptides is described. One-pot deallylation of a substrate through ruthenium hydride-catalyzed terminal olefin isomerization and subsequent ozonolysis gave the corresponding deallylated product under mild conditions.
Butylstannonic acid catalyzed transesterification of carboxylic esters
Furlan, Ricardo L. E.,Mata, Ernesto G.,Mascaretti, Oreste A.
, p. 2257 - 2260 (2007/10/03)
Butylstannonic acid is used as catalyst for transesterification of various carboxylic eaters. This method is also applicable to acetylation/deacetylation of alcohols.
Relative Partial Molar Enthalpies and Apparent Molar Volumes of Dipeptides in Aqueous Solution
Dyke, Shaun H.,Hedwig, Gavin R.,Watson, Ian D.
, p. 321 - 332 (2007/10/02)
Enthalpies of dilution at 25 deg C of aqueous solutions of the dipeptides glycylglycine, glycylalanine and alanylalanine have been determined and used to calculate the partial molar enthalpies of the solvent water in the solutions.The partial molar volumes of these dipeptides are also reported.The results are discussed in terms of the likely solute-solvent interactions.