388613-53-4

Basic information

• Product Name: Benzoic acid, 3,5-bis[[3-[(trimethylsilyl)ethynyl]phenyl]ethynyl]-, ethyl ester
• CAS NO: 388613-53-4
• Molecular Formula: C35H34O2Si2
• Molecular Weight: 542.825
• Mol File: 388613-53-4.mol

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 3,5-bis[[3-[(trimethylsilyl)ethynyl]phenyl]ethynyl]-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 3,5-bis[[3-[(trimethylsilyl)ethynyl]phenyl]ethynyl]-, ethyl ester(388613-53-4)
• EPA Substance Registry System: Benzoic acid, 3,5-bis[[3-[(trimethylsilyl)ethynyl]phenyl]ethynyl]-, ethyl ester(388613-53-4)

Safety Data

• Hazardous Substances Data: 388613-53-4(Hazardous Substances Data)

Upstream product

• 38170-79-5 1-ethynyl-3-<(trimethylsilyl)ethynyl>benzene 
• 388613-52-3 ethyl 3,5-diiodobenzoate 

Downstream Products

• 388613-56-7 C₇₁H₅₄O₆Si₂ 
• 388613-55-6 C₄₅H₂₈Br₂O₆ 
• 388613-54-5 3,5-bis-(3-ethynyl-phenylethynyl)-benzoic acid ethyl ester 

Relevant articles and documents

Solid-phase approaches toward cyclic oligomers

Strategies were sought to effect cyclizations of oligo(m-phenylene ethynylene) by exploiting pseudo-high dilution effects on polymer supports. Using Pd/Cu-catalyzed coupling protocols, Merrifield's resin (1% crosslinked chloromethylated polystyrene) proved inadequate for site isolation; inter-site couplings ensued on the flexible support. Conversely, use of the Argopore resin, a more highly crosslinked polystyrene, inhibited inter-site interactions, and no identifiable final product could be separated from the resin. Spectroscopic and mass spectrometric methods indicated that the product from the Argopore resin might be a threaded catenane.